{"id":"W2021533393","doi":"10.1021/bm0341327","title":"Physical Properties of Microbial Polythioesters:  Characterization of Poly(3-mercaptoalkanoates) Synthesized by Engineered <i>Escherichia coli</i>","year":2003,"lang":"en","type":"article","venue":"Biomacromolecules","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Solubility; Chloroform; Dissolution; Chemistry; Melting point; Thermal stability; Escherichia coli; Proton NMR; Thermal decomposition; Carbon-13 NMR; Sulfur; Nuclear chemistry; Polymer chemistry; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000151706,0.0002674678,0.0001015689,0.0001881014,0.00008358287,0.0002744243,0.00008682781,0.0002366064,0.0005192128],"category_scores_gemma":[0.0003605533,0.0001284607,0.0001708899,0.0001909043,0.0002184186,0.0002249691,0.000108215,0.000255743,0.0001812867],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001368306,"about_ca_system_score_gemma":0.000138977,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004241507,"about_ca_topic_score_gemma":0.0003615899,"domain_scores_codex":[0.9998621,0.00002399549,0.00001118044,0.0000275158,0.00005403318,0.00002116222],"domain_scores_gemma":[0.9997283,0.00006923026,0.00009770379,0.00001644568,0.00004698357,0.00004136073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001480837,0.000004001919,0.0002014751,0.00001485993,0.000001972398,0.00001613044,0.000008493565,0.00005510467,0.9991357,0.00000932375,0.000002745167,0.0005354068],"study_design_scores_gemma":[0.000001347114,0.0000708755,0.003617396,0.000002938036,0.000005797561,0.00006277785,0.00001217804,0.0002313005,0.9957081,0.000007529675,0.0002769667,0.000002704045],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995564,0.0008983244,0.002598611,0.00002750989,0.000006856012,0.00001407039,0.0001813002,0.00003014759,0.0006791528],"genre_scores_gemma":[0.9961487,0.0006196707,0.002050299,0.00002705986,0.000005053892,0.00002347893,0.0002261034,0.00002343232,0.0008761932],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005192128,"threshold_uncertainty_score":0.001736939,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01194807796455993,"score_gpt":0.1949310956625259,"score_spread":0.1829830176979659,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}