{"id":"W2021553179","doi":"10.1021/ja906430s","title":"Enhancing the Photochemical Stability of <i>N</i>,<i>C</i>-Chelate Boryl Compounds: C−C Bond Formation versus C═C Bond <i>cis,trans</i>-Isomerization","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":93,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Isomerization; Chromophore; Photochemistry; Double bond; Quenching (fluorescence); Photochromism; Molecule; Single bond; Polymer chemistry; Fluorescence; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001090606,0.0002458341,0.0001250335,0.0000797285,0.0001010797,0.0002452378,0.0001615911,0.000226263,0.001168488],"category_scores_gemma":[0.0001241482,0.0001132141,0.00007825842,0.0001053213,0.0001210671,0.0001841819,0.0001081373,0.0002349821,0.0002542667],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002623248,"about_ca_system_score_gemma":0.0001312898,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006390303,"about_ca_topic_score_gemma":0.001181976,"domain_scores_codex":[0.9999452,0.000008568302,0.000003193023,0.00001266425,0.00001094287,0.00001945297],"domain_scores_gemma":[0.9999384,0.00001235802,0.00002106356,0.000004428665,0.00001074056,0.00001304352],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004656231,0.000006270405,0.00004190822,0.00002049532,0.000001754959,0.000006091957,0.000008260516,0.00004227213,0.9991649,0.00004847614,0.00001131078,0.0006016277],"study_design_scores_gemma":[0.000005797818,0.0001113914,0.0004037346,0.000001532356,0.000003234156,0.00001768947,0.000006409763,0.0002026187,0.9987403,0.000005288436,0.0005000702,0.000001985565],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972687,0.0005855571,0.0006562248,0.00002633002,0.000005607167,0.00001050047,0.00006837941,0.00002644732,0.001352238],"genre_scores_gemma":[0.9975495,0.0003854234,0.001013295,0.00002062424,0.00000283374,0.00001304662,0.00006365814,0.00001231326,0.0009392882],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001168488,"threshold_uncertainty_score":0.003908992,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009221853501070673,"score_gpt":0.2369608893192453,"score_spread":0.2277390358181746,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}