{"id":"W2021648695","doi":"10.1016/s0162-0134(01)00394-4","title":"Copper speciation in the α and β domains of recombinant human metallothionein by electrospray ionization mass spectrometry","year":2002,"lang":"en","type":"article","venue":"Journal of Inorganic Biochemistry","topic":"Trace Elements in Health","field":"Nursing","cited_by":40,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Electrospray ionization; Metallothionein; Stoichiometry; Copper; Cadmium; Mass spectrometry; Crystallography; Metal; Electrospray; Oxidation state; Mass spectrum; Cluster (spacecraft); Transition metal; Inorganic chemistry; Physical chemistry; Organic chemistry; Chromatography; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007602228,0.0001203732,0.0002349898,0.0001046802,0.00008508338,0.00003165299,0.0002177474,0.0001221098,0.0001220036],"category_scores_gemma":[0.0001819762,0.0000941848,0.00004844592,0.0004147458,0.00005095419,0.0001232959,0.00001218352,0.0004398851,0.000001523389],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003008581,"about_ca_system_score_gemma":0.0000204589,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007979591,"about_ca_topic_score_gemma":0.000004769206,"domain_scores_codex":[0.9984929,0.0001071149,0.0006793902,0.0001318699,0.0003842951,0.0002044596],"domain_scores_gemma":[0.9988927,0.00008480225,0.0006990841,0.0001770305,0.00009734341,0.00004906616],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002782472,0.0002377345,0.0113169,0.00006220991,0.00002267222,0.000003367137,0.0004062291,7.759436e-7,0.9802595,0.00007986348,0.007256905,0.0003260077],"study_design_scores_gemma":[0.001355023,0.0004359067,0.01544669,0.00009504826,0.00005487123,0.0001459064,0.000442886,0.0000196208,0.9809593,0.000479882,0.0004407217,0.0001241458],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942054,0.001769781,0.0001362949,0.003200452,0.0002505407,0.0001037011,0.000003293984,0.000005856727,0.000324642],"genre_scores_gemma":[0.9983055,0.0002774528,0.000965342,0.000173159,0.000167414,8.045072e-7,0.000005349074,0.0000167298,0.00008825563],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006816183,"threshold_uncertainty_score":0.3840745,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009724025240048477,"score_gpt":0.2522640923991403,"score_spread":0.2425400671590918,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}