{"id":"W2021960014","doi":"10.1142/s1088424612500812","title":"Decoupling the artificial special pair to slow down the rate of singlet energy transfer","year":2012,"lang":"en","type":"article","venue":"Journal of Porphyrins and Phthalocyanines","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Trimer; Ultrafast laser spectroscopy; Chromophore; Porphyrin; Acceptor; Absorption spectroscopy; Photochemistry; Free base; Singlet state; Spectroscopy; Dimer; Crystallography; Excited state; Physical chemistry; Atomic physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008801583,0.000252611,0.0002620079,0.00008549899,0.0001159022,0.0001959013,0.0003456553,0.0002496347,0.001511963],"category_scores_gemma":[0.0001493866,0.0001251605,0.0001040793,0.0000864749,0.0001149246,0.0002035706,0.0002338201,0.0003349808,0.0003311024],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001623438,"about_ca_system_score_gemma":0.0001274564,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001668762,"about_ca_topic_score_gemma":0.0004515671,"domain_scores_codex":[0.9999497,0.000006412307,0.000002869006,0.00001801395,0.00001305787,0.000009947405],"domain_scores_gemma":[0.9999239,0.00001486121,0.00001868577,0.00001463566,0.00001032127,0.00001742153],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007862769,0.00002362541,0.0001084064,0.00003503597,0.00000843517,0.00002824616,0.0000127548,0.0003225482,0.9971955,0.0002722827,0.00004690361,0.00186771],"study_design_scores_gemma":[0.00002711538,0.0004656442,0.0005442227,0.000002914816,0.00001957325,0.0001257684,0.00001209986,0.006680642,0.9905067,0.00005932639,0.001549417,0.000006509552],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954026,0.0001774838,0.00352003,0.00003234256,0.00001688952,0.00001344943,0.00002870271,0.000071574,0.0007370089],"genre_scores_gemma":[0.9947575,0.0001013352,0.004001733,0.00002785034,0.000004781898,0.00002001607,0.00004112886,0.00002034678,0.001025307],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001511963,"threshold_uncertainty_score":0.005057991,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02062012468711349,"score_gpt":0.2401853582897787,"score_spread":0.2195652336026652,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}