{"id":"W2022575680","doi":"10.1002/anie.200604258","title":"Persistent Silylium Ions Stabilized by Polyagostic SiH⋅⋅⋅Si Interactions","year":2007,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Agostic interaction; Cationic polymerization; Ion; Silicon; Center (category theory); Crystallography; Chemistry; Silanes; Materials science; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001795862,0.0002156936,0.0001576697,0.0001026178,0.0001909144,0.00008379293,0.0002910865,0.0001814111,0.007294103],"category_scores_gemma":[0.0002099663,0.0002147965,0.0002162961,0.000164886,0.00008654737,0.0002807369,0.00007815178,0.0004465802,0.0001377411],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006214759,"about_ca_system_score_gemma":0.00006042455,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001058587,"about_ca_topic_score_gemma":0.00003130046,"domain_scores_codex":[0.998399,0.000006371151,0.0004278755,0.0003451272,0.0004532793,0.0003683203],"domain_scores_gemma":[0.9988539,0.0002301103,0.0001695115,0.000232755,0.0003504961,0.0001632515],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009832464,0.0002517708,0.0002089847,0.00002078739,0.0002306017,0.00001644948,0.000259247,0.00001106318,0.9443489,0.000385991,0.0536474,0.0005204267],"study_design_scores_gemma":[0.0007964326,0.0000224714,0.00004005941,0.00007349752,0.00007109378,0.00008905709,0.001004793,0.0002047223,0.8515796,0.000237352,0.1456458,0.0002351073],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4884447,0.0008873048,0.008112497,0.006333728,0.010835,0.0002128592,0.0007167053,0.0006340751,0.4838231],"genre_scores_gemma":[0.9835082,0.00009163729,0.0001431355,0.0002512561,0.001992547,0.00001952867,0.001772792,0.00003468144,0.01218619],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4950635,"threshold_uncertainty_score":0.9936134,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01019686232723744,"score_gpt":0.2470371236114738,"score_spread":0.2368402612842364,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}