{"id":"W2022701978","doi":"10.1007/s00216-012-6505-6","title":"Solution to peptide sequencing challenge","year":2013,"lang":"en","type":"article","venue":"Analytical and Bioanalytical Chemistry","topic":"Biochemical and Structural Characterization","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Peptide; Disulfide bond; Chemistry; Cyclic peptide; Cystine; Cysteine; Peptide sequence; Amino acid; Stereochemistry; Biochemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006701681,0.0002043974,0.0001917931,0.00002027717,0.00007655757,0.00006518317,0.0001400022,0.0002358544,0.0003129558],"category_scores_gemma":[0.0001591059,0.0001638854,0.00009457659,0.0001379346,0.0001497207,0.000009775335,0.0001738866,0.0001396387,0.00007528284],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000273012,"about_ca_system_score_gemma":0.0000287195,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000031183,"about_ca_topic_score_gemma":0.000002274075,"domain_scores_codex":[0.9987168,0.00001340699,0.0002535774,0.0004929909,0.0001664896,0.0003567365],"domain_scores_gemma":[0.9991767,0.00001353583,0.00003344679,0.000227623,0.0001123279,0.0004363609],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002349657,0.00002398407,0.0006126719,0.00004136039,0.00004150513,0.000002081722,0.000008315587,0.000001207229,0.9948649,0.0001771749,0.001540813,0.002662496],"study_design_scores_gemma":[0.0007275213,0.0003787086,0.009852371,0.00006594094,0.0001470646,0.00009709483,0.0001628187,0.01239667,0.9524264,0.00189847,0.02061849,0.001228507],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887094,0.0001030943,0.0008055132,0.004223364,0.00002426125,0.0001282141,0.00001075671,0.00002640451,0.005968915],"genre_scores_gemma":[0.9955667,0.00005305092,0.0004418291,0.0008068137,0.0003756183,0.00001523112,0.0001052391,0.00001368614,0.002621882],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04243854,"threshold_uncertainty_score":0.6683052,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01202238146921742,"score_gpt":0.2279539715670183,"score_spread":0.2159315900978009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}