{"id":"W2022798812","doi":"10.1002/ejic.200400867","title":"The Hexakis(thiocyanato)ferrate(<scp>III</scp>) Ion: a Coordination Chemistry Classic Reveals an Interesting Geometry Pattern for the Thiocyanate Ligands","year":2005,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Drexel University","keywords":"Chemistry; Thiocyanate; Monoclinic crystal system; Crystallography; Coordination geometry; Electron paramagnetic resonance; Ion; Coordination complex; Mössbauer spectroscopy; Infrared spectroscopy; Copper; Crystal structure; Stereochemistry; Inorganic chemistry; Molecule; Metal; Nuclear magnetic resonance; Hydrogen bond; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.004409816,0.0003665522,0.0003662804,0.00004694011,0.0008203506,0.0006994864,0.002058008,0.00009655607,0.0004368779],"category_scores_gemma":[0.002393322,0.000248095,0.0002044003,0.0003545356,0.0002573943,0.0004555488,0.000326578,0.0007107402,0.00004724695],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000203114,"about_ca_system_score_gemma":0.0001752794,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003609597,"about_ca_topic_score_gemma":0.000004275484,"domain_scores_codex":[0.996825,0.0002296927,0.001317415,0.0004208155,0.0006629418,0.0005441807],"domain_scores_gemma":[0.9952179,0.001454351,0.001561331,0.0007260659,0.0007987361,0.0002415758],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002524908,0.00006661307,0.0001355778,0.00009712247,0.0000432438,0.00002543774,0.0004836565,0.00009646049,0.9700948,0.00002208291,0.01290685,0.01600289],"study_design_scores_gemma":[0.00133097,0.0001275764,0.001328773,0.0001965648,0.00008422419,0.0006853499,0.001657646,0.001711982,0.965,0.000139302,0.02753333,0.0002043059],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9847035,0.001413538,0.005556151,0.003132754,0.0007357697,0.0002098677,0.00002134024,0.00008683385,0.004140252],"genre_scores_gemma":[0.9924029,0.00008726184,0.0003851084,0.0003681079,0.002861805,0.000007740272,0.000009360096,0.00008115736,0.003796575],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01579858,"threshold_uncertainty_score":0.9999971,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02043048630710723,"score_gpt":0.2536781604297348,"score_spread":0.2332476741226276,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}