{"id":"W2022806379","doi":"10.1021/om0494420","title":"Influence of SiMe<sub>3</sub> Substituents on Structures and Hydrosilylation Activities of ((SiMe<sub>3</sub>)<sub>1</sub> <sub>or</sub><sub> </sub><sub>2</sub><b>-</b>Indenyl)Ni(PPh<sub>3</sub>)Cl","year":2004,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Hydrosilylation; Steric effects; Moiety; Reactivity (psychology); Cationic polymerization; Styrene; Medicinal chemistry; Catalysis; Ligand (biochemistry); Lability; Stereochemistry; Substituent; Silylation; Trans effect; Crystallography; Crystal structure; Polymer chemistry; Organic chemistry; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.002472744,0.005969949,0.006958703,0.003529002,0.00232819,0.001480916,0.004378415,0.00370951,0.0005313439],"category_scores_gemma":[0.002384744,0.006359515,0.002966192,0.006942445,0.003568801,0.004007454,0.00255157,0.004175973,0.0008584695],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002606821,"about_ca_system_score_gemma":0.002186384,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001629444,"about_ca_topic_score_gemma":0.001456745,"domain_scores_codex":[0.9735856,0.001020841,0.006957418,0.006586944,0.006397613,0.005451565],"domain_scores_gemma":[0.9805747,0.002277578,0.005935723,0.006660094,0.001853731,0.002698214],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001424476,0.002941074,0.002059892,0.002479025,0.00317514,0.000315397,0.001645383,0.005435165,0.9395791,0.0005364851,0.0004633419,0.0399455],"study_design_scores_gemma":[0.006173439,0.0008770182,0.01824648,0.001426183,0.003349707,0.0003774718,0.0009884561,0.0003848722,0.9592354,0.002215634,0.0007170334,0.006008271],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9856511,0.002381271,0.0004173155,0.0003557948,0.001096941,0.002659906,0.005574575,0.00120532,0.0006577486],"genre_scores_gemma":[0.9839553,0.007210149,0.0002087961,0.0005732426,0.001489047,0.0005269712,0.0044869,0.001496211,0.00005333368],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03393723,"threshold_uncertainty_score":0.9999195,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01083621461552835,"score_gpt":0.2139197658662435,"score_spread":0.2030835512507151,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}