{"id":"W2023022398","doi":"10.1016/j.poly.2005.08.020","title":"Self-assembly of organometallic polymers through hydrogen bonding: A diplatinum(IV) complex with a single bridging halide ligand","year":2005,"lang":"en","type":"article","venue":"Polyhedron","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Hydrogen bond; Bromide; Oxidative addition; Halide; Ligand (biochemistry); Intermolecular force; Crystallography; Bridging ligand; Platinum; Polymer chemistry; Stereochemistry; Crystal structure; Molecule; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007516179,0.0001516455,0.0001685078,0.0001173346,0.0002031438,0.0005597434,0.0003207719,0.0001949053,0.001215394],"category_scores_gemma":[0.0001110888,0.0001853266,0.0001032408,0.00009076198,0.0001666355,0.000277156,0.0003130925,0.0003186222,0.000303315],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002247984,"about_ca_system_score_gemma":0.0001246218,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002622753,"about_ca_topic_score_gemma":0.0003854611,"domain_scores_codex":[0.9999378,0.000007827934,0.000004266743,0.00001561427,0.00001491915,0.00001962797],"domain_scores_gemma":[0.999943,0.00000952228,0.00001272669,0.000009483773,0.000004187768,0.00002104217],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001886102,0.00007370031,0.0001707787,0.00008018685,0.00001491295,0.0001519263,0.0001117113,0.001119449,0.9886754,0.003281473,0.0003458546,0.005786024],"study_design_scores_gemma":[0.00006407624,0.0002622382,0.0003876768,0.000003530497,0.00001252458,0.00009847382,0.00003441875,0.004863932,0.9896623,0.0002601446,0.004338182,0.00001262464],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887617,0.0003412934,0.004742485,0.00009281639,0.00003450865,0.00002871079,0.00004266072,0.0001302507,0.005825524],"genre_scores_gemma":[0.9952425,0.00011206,0.001801403,0.00002580486,0.000004530119,0.00001406431,0.00003432695,0.00002018797,0.0027452],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001215394,"threshold_uncertainty_score":0.004065931,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02014841212472475,"score_gpt":0.2304357421771533,"score_spread":0.2102873300524285,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}