{"id":"W2023049214","doi":"10.1021/jf103194k","title":"Dimerization of Azomethine Ylides: An Alternate Route to Pyrazine Formation in the Maillard Reaction","year":2010,"lang":"en","type":"article","venue":"Journal of Agricultural and Food Chemistry","topic":"Synthesis and Biological Evaluation","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Maillard reaction; Pyrazine; Chemistry; Azomethine ylide; Organic chemistry; Combinatorial chemistry; Cycloaddition; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003178412,0.00008634328,0.0001452324,0.00001595649,0.00003319206,0.00002947132,0.0001329119,0.0001079299,0.00004261766],"category_scores_gemma":[0.0001679974,0.00003960238,0.00005253092,0.0001073096,0.00001922171,0.0002300006,0.00001534489,0.0002269276,4.48265e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001772562,"about_ca_system_score_gemma":0.000006069904,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006570485,"about_ca_topic_score_gemma":0.00001052853,"domain_scores_codex":[0.9992335,0.00001470889,0.0003739397,0.00007826045,0.0002195854,0.00007995062],"domain_scores_gemma":[0.9993017,0.00004800323,0.0003645351,0.00007296324,0.0001610469,0.0000517152],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003248615,0.00005620211,0.0008351301,0.00003994873,0.0000108601,4.893876e-7,0.0002184524,0.00001767639,0.9946755,0.00001244482,0.00002010814,0.004080715],"study_design_scores_gemma":[0.0002655181,0.0001080804,0.103496,0.00005353284,0.00002594952,0.0002381435,0.0009219865,0.00003134073,0.8944097,0.0001784856,0.0001959066,0.0000753959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985612,0.00004008087,0.00001214647,0.0006509784,0.00004105575,0.00003158949,0.000007056374,0.000004589703,0.0006512858],"genre_scores_gemma":[0.9993478,0.00006452769,0.0002061418,0.00003392014,0.0002835245,0.000002301867,0.00002941163,0.0000022481,0.00003009877],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1026609,"threshold_uncertainty_score":0.1614938,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01921045376535226,"score_gpt":0.2478497610280635,"score_spread":0.2286393072627112,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}