{"id":"W2023319262","doi":"10.1021/ja027080m","title":"Parallel Modes of C−H Bond Activation Initiated by Cp*Mo(NO)(CH<sub>2</sub>CMe<sub>3</sub>)(C<sub>6</sub>H<sub>5</sub>) at Ambient Temperatures","year":2002,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Neopentane; Molybdenum; Aryne; Intermolecular force; Adduct; Thermal decomposition; Benzene; Hydrocarbon; Pyridine; X-ray crystallography; Crystallography; Stereochemistry; Decomposition; Molecule; Medicinal chemistry; Diffraction; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001221737,0.0002927288,0.0001453618,0.0001801111,0.0002704792,0.0002447221,0.0003327638,0.0002219861,0.002620214],"category_scores_gemma":[0.0002277547,0.0002217705,0.0001115331,0.0001023795,0.000397617,0.0003279549,0.0002845445,0.0003383161,0.0003004697],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002700457,"about_ca_system_score_gemma":0.0001357326,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004036468,"about_ca_topic_score_gemma":0.0007968681,"domain_scores_codex":[0.9998989,0.000006602409,0.000002530768,0.00003010153,0.00003161691,0.00003022805],"domain_scores_gemma":[0.9998897,0.00003000055,0.0000274993,0.00001983339,0.00001673273,0.00001617384],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004814305,0.00004164795,0.0009395177,0.00009142651,0.000009252226,0.00009568778,0.0001996918,0.0004167083,0.9888988,0.002175936,0.0001638702,0.006486086],"study_design_scores_gemma":[0.00003576257,0.0001735002,0.002585643,0.000004974499,0.000008771177,0.0001669116,0.00006409214,0.002355679,0.9927344,0.0004920391,0.001366354,0.00001182801],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921864,0.0002038184,0.002481429,0.00002685168,0.00001375052,0.00002851556,0.00007099428,0.00005290943,0.004935245],"genre_scores_gemma":[0.9974205,0.0001180728,0.0009761702,0.000009759998,0.000002758521,0.00001935602,0.0000317653,0.000009045325,0.001412562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002620214,"threshold_uncertainty_score":0.008765519,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01372554600462087,"score_gpt":0.2164441678448642,"score_spread":0.2027186218402433,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}