{"id":"W2023587691","doi":"10.1016/j.chroma.2005.02.030","title":"Effect of anionic additive type on ion pair formation constants of basic pharmaceuticals","year":2005,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":57,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"National Institutes of Health","keywords":"Chemistry; Cationic polymerization; Chromatography; Perchlorate; Acetonitrile; Ion chromatography; Electrospray ionization; Chloride; Ion; Mass spectrometry; Solvent; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006936616,0.0003961907,0.0003105456,0.0002752796,0.0002326815,0.000613267,0.0003860135,0.0003570018,0.002869779],"category_scores_gemma":[0.002217718,0.0003304213,0.0002395781,0.0002680376,0.000254178,0.0005149927,0.0003283572,0.0004392074,0.0006223957],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002832948,"about_ca_system_score_gemma":0.0003824674,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006653417,"about_ca_topic_score_gemma":0.0007044271,"domain_scores_codex":[0.9994166,0.0002016995,0.00006357259,0.00009359308,0.0001347555,0.00008971724],"domain_scores_gemma":[0.9986838,0.0007706564,0.0001413148,0.00007241593,0.0002075439,0.0001243968],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.006250602,0.0001723324,0.0008614896,0.0001859594,0.00007518436,0.0001440432,0.0001038042,0.0007707253,0.9773225,0.0002561096,0.000193304,0.01366395],"study_design_scores_gemma":[0.00002613309,0.0005550963,0.000679318,0.000005330996,0.00004851583,0.00007176495,0.00002253304,0.0005720835,0.9971707,0.00002325957,0.0008164779,0.000008740411],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943627,0.001714253,0.001369802,0.00007362364,0.00007913518,0.00002981262,0.0001022848,0.00005558009,0.002212781],"genre_scores_gemma":[0.9959041,0.0008560077,0.001351685,0.00006532961,0.00002884662,0.00001117567,0.00008076998,0.00001990076,0.001682127],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002869779,"threshold_uncertainty_score":0.009600401,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01119799504069993,"score_gpt":0.2837629459744637,"score_spread":0.2725649509337638,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}