{"id":"W2023613739","doi":"10.1038/nchem.653","title":"Mechanistic insights into the ruthenium-catalysed diene ring-closing metathesis reaction","year":2010,"lang":"en","type":"article","venue":"Nature Chemistry","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":86,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Ruthenium; Ring-closing metathesis; Diene; Salt metathesis reaction; Metathesis; Closing (real estate); Acyclic diene metathesis; Combinatorial chemistry; Organic chemistry; Catalysis; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["research_integrity"],"category_scores_codex":[0.000510959,0.0005238882,0.0004295712,0.00002958907,0.0004330449,0.0001216238,0.001074973,0.00143133,0.002049333],"category_scores_gemma":[0.002768406,0.0004022644,0.0002764091,0.0003529449,0.0002567226,0.0001135018,0.0002399691,0.003450138,0.00004883924],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000193248,"about_ca_system_score_gemma":0.0001448683,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002701358,"about_ca_topic_score_gemma":0.00001059007,"domain_scores_codex":[0.9974694,0.00003203492,0.0004835473,0.0008751327,0.000647043,0.0004928508],"domain_scores_gemma":[0.9966224,0.0007883424,0.0003409027,0.00183328,0.0001790757,0.0002360222],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003385656,0.00008474915,0.00001448512,0.0002304307,0.0001161149,0.00001716011,0.0005145144,4.302626e-7,0.993954,0.000125277,0.0001144108,0.004794595],"study_design_scores_gemma":[0.000377979,0.000002381172,0.00002185711,0.00006106155,0.0002563502,0.0001396955,0.0004367353,0.0001768719,0.967262,0.002650434,0.02815809,0.0004565391],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9457133,0.0009040603,0.0001790704,0.0006300395,0.0005928965,0.00007945004,0.00001019569,0.0003739393,0.051517],"genre_scores_gemma":[0.9917215,0.0000357508,0.00385126,0.0001166117,0.001390499,0.00004447343,0.00006887127,0.000107871,0.002663214],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04885379,"threshold_uncertainty_score":0.999865,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006855282091392652,"score_gpt":0.2587671032907564,"score_spread":0.2519118211993637,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}