{"id":"W2023745768","doi":"10.1039/c5dt00822k","title":"Catalytic aerobic oxidation of phenols to ortho-quinones with air-stable copper precatalysts","year":2015,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Concordia University","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada","keywords":"Phenols; Copper; Catalysis; Chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002411932,0.000250787,0.000329723,0.0002051002,0.000115514,0.0000290018,0.0002690524,0.0001277269,0.0006745287],"category_scores_gemma":[0.00003682263,0.000236242,0.00008861251,0.0006073692,0.00005683608,0.0004292285,0.00001121822,0.0001667792,0.0002478625],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001495858,"about_ca_system_score_gemma":0.00024299,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002704098,"about_ca_topic_score_gemma":0.0003808786,"domain_scores_codex":[0.9982215,0.00002935376,0.0004543989,0.0004319724,0.0005390536,0.0003237746],"domain_scores_gemma":[0.9983977,0.00005290926,0.00017937,0.0006946128,0.0003390854,0.000336312],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002469592,0.0004605129,0.0001104798,0.0002851977,0.0002427529,0.000006530373,0.002239269,0.0148155,0.9775535,0.0006652483,0.0006551079,0.002718925],"study_design_scores_gemma":[0.0009984601,0.00007506853,0.00004665052,0.00006680991,0.0001767361,0.00003374499,0.0008842601,0.0002125728,0.9914203,0.00007556885,0.005715073,0.0002947343],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7994806,0.00008943836,0.1836132,0.0004182434,0.0002155325,0.0005021191,0.0002688669,0.0002799843,0.01513211],"genre_scores_gemma":[0.9888806,0.000006642929,0.004857099,0.00005244169,0.0000374377,0.00009996894,0.0005828997,0.00005528138,0.00542758],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1894001,"threshold_uncertainty_score":0.9633671,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02681024530838762,"score_gpt":0.2504750258247286,"score_spread":0.223664780516341,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}