{"id":"W2023765913","doi":"10.1002/jms.1898","title":"Electron‐bombardment matrix isolation and PEPICO studies as complementary techniques in ion chemistry: an FTIR study of the decomposition of the vinyl fluoride cation","year":2011,"lang":"en","type":"article","venue":"Journal of Mass Spectrometry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trent University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Photoionization; Reagent; Matrix isolation; Ion; Ionization; Electron ionization; Analytical Chemistry (journal); Fluoride; Decomposition; Fourier transform infrared spectroscopy; Matrix (chemical analysis); Mass spectrometry; Computational chemistry; Physical chemistry; Molecule; Inorganic chemistry; Organic chemistry; Chromatography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003895385,0.0006122931,0.0003289055,0.000341489,0.0003199833,0.0003210647,0.0004424219,0.000498444,0.001561735],"category_scores_gemma":[0.0004959549,0.0002400514,0.000242171,0.0003240689,0.0003795701,0.0005378361,0.0003379126,0.0008499225,0.0002595464],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002270031,"about_ca_system_score_gemma":0.0001372763,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006666273,"about_ca_topic_score_gemma":0.0008507242,"domain_scores_codex":[0.999734,0.00003375358,0.000009997303,0.00006445342,0.0001071458,0.00005067235],"domain_scores_gemma":[0.9996849,0.0001258239,0.00005874109,0.00002584735,0.00008081531,0.00002387598],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005220051,0.000007728767,0.0001930402,0.00002418879,0.000004482056,0.00003148651,0.00002165772,0.00002496333,0.998702,0.00002985418,0.00001112841,0.0008972011],"study_design_scores_gemma":[0.000005945035,0.0001384451,0.00397958,0.000005031945,0.000007566266,0.000200735,0.00003841906,0.0002840807,0.9947032,0.0000246738,0.0006080698,0.000004248587],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9811318,0.002147507,0.01345525,0.0001017518,0.00003692411,0.00008736882,0.0002963436,0.00008473465,0.002658381],"genre_scores_gemma":[0.9739118,0.002227092,0.02132876,0.00009160227,0.00001657118,0.00007681223,0.000449899,0.00004309109,0.001854485],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001561735,"threshold_uncertainty_score":0.005224526,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01389380985554604,"score_gpt":0.2854479190616551,"score_spread":0.271554109206109,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}