{"id":"W2023860819","doi":"10.1139/cjc-2014-0358","title":"Structure and reactivity of phosphate diesters. Dependence on the nonleaving group","year":2015,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Reactivity (psychology); Hydrolysis; Group (periodic table); Leaving group; Phosphate; Molecule; Stereochemistry; Computational chemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001980479,0.0001335222,0.0001981315,0.0000203203,0.00005018678,0.0000361671,0.0002806234,0.0001388488,0.0004974849],"category_scores_gemma":[0.0007256416,0.0001021381,0.00006237187,0.00006790951,0.0001255681,0.0001021447,0.00002106562,0.000536551,0.000001100198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002236187,"about_ca_system_score_gemma":0.0004674791,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004903807,"about_ca_topic_score_gemma":0.0003734432,"domain_scores_codex":[0.999141,0.000008872243,0.0002546559,0.0001281425,0.0002646428,0.0002026477],"domain_scores_gemma":[0.998512,0.0001497949,0.0003374887,0.0002327494,0.0001539639,0.0006140149],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003650076,0.000008242756,0.0007638505,0.00005807159,0.00002729829,0.0000607843,0.0002456386,0.000005859348,0.9962908,0.00003246212,0.000467595,0.002002879],"study_design_scores_gemma":[0.0002913976,0.0000150115,0.00008324367,0.0001571449,0.00001901153,0.0003325788,0.0008426543,0.00001571067,0.995821,0.0006930646,0.001628407,0.0001007679],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944565,0.0002665317,0.00001876237,0.0003471269,0.00008402359,0.00001633219,0.00002984972,0.000004010523,0.00477683],"genre_scores_gemma":[0.9994455,0.00001104715,0.00008333124,0.00008287743,0.0001491406,3.869925e-7,0.000001896186,0.0000144011,0.0002114421],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004988945,"threshold_uncertainty_score":0.5447111,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01652860182648377,"score_gpt":0.2116234317366164,"score_spread":0.1950948299101326,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}