{"id":"W2023909306","doi":"10.1139/v99-252","title":"Enantioselective synthesis of syringolide 2 from D-arabinose","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Arabinose; Enantioselective synthesis; Derivative (finance); Stereochemistry; Organic chemistry; Catalysis; Fermentation; Xylose","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001352131,0.0002339165,0.0005042942,0.00004825883,0.0000850627,0.00004012239,0.0005403447,0.0002596902,0.0325826],"category_scores_gemma":[0.0004891017,0.0002397688,0.0003213955,0.0001655954,0.0001973753,0.0001164211,0.000008705028,0.0003829285,0.00001613136],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002357258,"about_ca_system_score_gemma":0.001114241,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002833538,"about_ca_topic_score_gemma":0.0003464394,"domain_scores_codex":[0.998491,0.00001464868,0.0006577732,0.000217768,0.0002383469,0.0003804229],"domain_scores_gemma":[0.9980533,0.0002776464,0.0003683375,0.0003807422,0.0002091087,0.0007108419],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006971736,0.0000372476,0.002115502,0.0001498581,0.000222343,0.0002580611,0.0003098428,0.00005044411,0.9847876,0.000001518278,0.0008209826,0.0111769],"study_design_scores_gemma":[0.0002600653,0.000004634772,0.0002514315,0.0003911173,0.0001025066,0.0001630597,0.0003169838,0.00001391022,0.9902607,0.0001961177,0.007809943,0.0002295866],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8959596,0.0006236411,0.00000169228,0.00009885318,0.00003714591,0.00001266232,0.0002152721,0.000008981448,0.1030422],"genre_scores_gemma":[0.9972595,0.00008245587,0.00009196735,0.00002284845,0.0004227219,0.000003081002,0.000009695787,0.00003071387,0.002077009],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1013,"threshold_uncertainty_score":0.9777489,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006080944863472128,"score_gpt":0.1822042964791113,"score_spread":0.1761233516156391,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}