{"id":"W2024075695","doi":"10.1039/c4py00680a","title":"Silicone dendrons and dendrimers from orthogonal SiH coupling reactions","year":2014,"lang":"en","type":"article","venue":"Polymer Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Dendrimer; Hydrosilylation; Silicone; Yield (engineering); Polymer chemistry; Silsesquioxane; Materials science; Coupling (piping); Chemistry; Catalysis; Composite material; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005179864,0.0007350235,0.0003280268,0.0004793504,0.0003018214,0.0002856682,0.0003144257,0.0003314568,0.001603916],"category_scores_gemma":[0.0003063097,0.0004038456,0.0003767912,0.0003858647,0.0003492085,0.0004964839,0.0007175048,0.0008573671,0.00110272],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004139825,"about_ca_system_score_gemma":0.0004563378,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00020515,"about_ca_topic_score_gemma":0.0006906761,"domain_scores_codex":[0.9997163,0.00003273299,0.00002639837,0.00005463613,0.00008340753,0.00008637107],"domain_scores_gemma":[0.9998611,0.0000260887,0.00002269427,0.00003247305,0.00003141264,0.00002619406],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008794211,0.00002352498,0.00009443769,0.00009510696,0.000008031223,0.0001982812,0.0001117211,0.0005425084,0.9883829,0.00291508,0.0001922878,0.007348217],"study_design_scores_gemma":[0.000009859454,0.00008094562,0.000150104,0.000003505868,0.000006383323,0.0001324705,0.000006842874,0.000575552,0.9955267,0.0002365403,0.003261898,0.000009214225],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8720012,0.001978242,0.09541091,0.0003038187,0.0001801149,0.0002964399,0.0005455854,0.0009147199,0.02836889],"genre_scores_gemma":[0.9375859,0.0021476,0.04827853,0.00007518124,0.00003495055,0.0001341432,0.0006311032,0.0001512655,0.01096113],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001603916,"threshold_uncertainty_score":0.00536561,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008169727303426041,"score_gpt":0.229413826491708,"score_spread":0.221244099188282,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}