{"id":"W2024232265","doi":"10.1016/j.chemosphere.2009.11.014","title":"Kinetics and mechanism of the degradation of two pesticides in aqueous solutions by ozonation","year":2009,"lang":"en","type":"article","venue":"Chemosphere","topic":"Advanced oxidation water treatment","field":"Environmental Science","cited_by":87,"is_retracted":false,"has_abstract":false,"ca_institutions":"Canadian Natural Resources; University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta","keywords":"Chemistry; Trifluralin; Reaction rate constant; Hydroxylation; Hydroxyl radical; Photochemistry; Radical; Kinetics; Ozone; Radiolysis; Bromoxynil; Reaction mechanism; Aqueous solution; Organic chemistry; Pesticide; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002490726,0.0004144611,0.0002171432,0.0002063235,0.0001774236,0.0003710912,0.0003180993,0.0005126017,0.001145199],"category_scores_gemma":[0.0004065309,0.0002207364,0.0002476047,0.0001538353,0.0004016493,0.0004267349,0.000182824,0.0004715248,0.0002484155],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005470367,"about_ca_system_score_gemma":0.0003497382,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002616974,"about_ca_topic_score_gemma":0.001325297,"domain_scores_codex":[0.9998701,0.00001413966,0.000007965939,0.00002437691,0.00003835765,0.00004503063],"domain_scores_gemma":[0.9998368,0.00006264592,0.00003754572,0.000006800808,0.00004136758,0.00001482501],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007783737,0.00004214158,0.0009268795,0.0001103323,0.00001876628,0.00009496152,0.0001169166,0.001296607,0.9912575,0.0005374306,0.000086986,0.004733137],"study_design_scores_gemma":[0.00003176378,0.0003244166,0.002506559,0.000005478544,0.00001735868,0.00006855855,0.0000541739,0.005106377,0.9908597,0.0001952314,0.0008155498,0.00001483809],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9953108,0.0008730076,0.002902614,0.00009167325,0.00001933727,0.00001809224,0.0001040791,0.00002222063,0.0006582031],"genre_scores_gemma":[0.9973942,0.0004703414,0.000655901,0.0000170889,0.000005580594,0.000007268735,0.00007457651,0.000004029784,0.001370935],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002616974,"threshold_uncertainty_score":0.005203545,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00879262014507056,"score_gpt":0.2221939795886107,"score_spread":0.2134013594435401,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}