{"id":"W2024246539","doi":"10.1560/qrh5-q3n0-0xa6-pt9y","title":"On the relative rate of hydrolysis of a series of ketals and their proton affinities","year":2000,"lang":"en","type":"article","venue":"Israel Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Protonation; Affinities; Proton affinity; Hydrolysis; Proton; Reactivity (psychology); Computational chemistry; Bond cleavage; Cleavage (geology); Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003093668,0.0001662438,0.0004561262,0.00002314745,0.00002692433,0.000008823604,0.000233829,0.0001357483,0.001636542],"category_scores_gemma":[0.0003917898,0.0001073763,0.0002226011,0.0001004285,0.0002818639,0.0001286171,0.00003066495,0.0003423837,7.770432e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002822449,"about_ca_system_score_gemma":0.00007252509,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005617699,"about_ca_topic_score_gemma":1.944365e-7,"domain_scores_codex":[0.998823,0.0000258765,0.0006780087,0.0001112804,0.0002425773,0.0001192999],"domain_scores_gemma":[0.9979335,0.0005888635,0.0009551829,0.0002485497,0.0002119521,0.00006196999],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000559754,0.0001065543,0.00006423331,0.0003890309,0.0002001777,0.000003562017,0.0005279171,0.00001933647,0.9972314,0.0001734654,0.00003701404,0.0006876175],"study_design_scores_gemma":[0.0004760161,0.00006114863,0.00001123799,0.0004767057,0.00005901727,0.00008340741,0.001334905,0.00001896023,0.9891044,0.007986369,0.0003021761,0.00008562858],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9813759,0.000253493,0.000008402132,0.0002100478,0.000009260021,0.00005081479,0.000039691,0.000005279852,0.0180471],"genre_scores_gemma":[0.9983069,0.0002505746,0.00007855672,0.00002100195,0.00004631939,0.000005472048,0.000001825604,0.00001521923,0.001274156],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01693097,"threshold_uncertainty_score":0.9992761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01081498862676056,"score_gpt":0.211201591948063,"score_spread":0.2003866033213024,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}