{"id":"W2024451700","doi":"10.1002/chem.200902014","title":"Binuclear Uranium(VI) Complexes with a “Pacman” Expanded Porphyrin: Computational Evidence for Highly Unusual Bis‐Actinyl Structures","year":2010,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid","keywords":"Porphyrin; Uranium; Chemistry; Combinatorial chemistry; Materials science; Photochemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003367429,0.0005902543,0.0009315264,0.0003251942,0.0005164374,0.0006565521,0.001368642,0.0009547662,0.003308156],"category_scores_gemma":[0.0005937775,0.0005025163,0.0004208652,0.0003588772,0.0004760625,0.0005145854,0.0005841489,0.0007478006,0.0001925298],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008980741,"about_ca_system_score_gemma":0.0009534768,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.005471145,"about_ca_topic_score_gemma":0.008932951,"domain_scores_codex":[0.9998847,0.00003485674,0.000003245461,0.00001562066,0.00002638935,0.0000352072],"domain_scores_gemma":[0.9998145,0.0000953711,0.00001882817,0.00001926456,0.00003008584,0.00002207573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.000556622,0.000259695,0.003728095,0.0003648372,0.0001331153,0.0004450858,0.0001562745,0.9613097,0.01107446,0.01114073,0.001650456,0.009180862],"study_design_scores_gemma":[0.0002156545,0.0002441042,0.0008846227,0.00001971131,0.0000405473,0.00004343404,0.0001506309,0.9927883,0.002532365,0.002234205,0.0008342381,0.00001218611],"study_design_candidate":"simulation_or_modeling","study_design_consensus":"simulation_or_modeling","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9885193,0.0002115675,0.004863332,0.0001871232,0.00001637513,0.0000379611,0.0002766555,0.0001340325,0.005753679],"genre_scores_gemma":[0.9899553,0.0001731669,0.008604485,0.00009179614,0.000006496604,0.0000992515,0.0004314022,0.00006011933,0.0005778916],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005471145,"threshold_uncertainty_score":0.01106685,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03805719635673625,"score_gpt":0.2859601563524388,"score_spread":0.2479029599957026,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}