{"id":"W2024501283","doi":"10.1021/ac000358d","title":"Ferricyanide Reduction by <i>Escherichia </i><i>c</i><i>oli</i>:  Kinetics, Mechanism, and Application to the Optimization of Recombinant Fermentations","year":2000,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Cassava research and cyanide","field":"Agricultural and Biological Sciences","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada; University of Waterloo","keywords":"Ferricyanide; Chemistry; Formate; Cytochrome c; Escherichia coli; Nuclear chemistry; Cytochrome; Biochemistry; Chromatography; Enzyme; Mitochondrion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000122353,0.00008949423,0.0001042307,0.000003642543,0.0001161388,0.00004103161,0.000147678,0.00006048875,0.0008379132],"category_scores_gemma":[0.0000345375,0.00003832005,0.00004179786,0.0003307976,0.00005937608,0.0000486964,0.00003149282,0.00009121343,0.00001526508],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002284227,"about_ca_system_score_gemma":0.000005865437,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002135171,"about_ca_topic_score_gemma":0.0000252816,"domain_scores_codex":[0.9991854,0.00002546874,0.0001887504,0.0002281047,0.0001948056,0.0001774079],"domain_scores_gemma":[0.9996383,0.00004717456,0.00003819959,0.00007883579,0.00006016923,0.000137334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003183392,0.0001075857,0.00005219,0.000007410682,0.00001024241,2.519564e-7,0.00001840341,0.0003207882,0.9806855,0.0001337166,0.00452082,0.0141113],"study_design_scores_gemma":[0.0005916057,0.0006147851,0.004294748,0.00004607822,0.0001467053,0.00004888084,0.001014205,0.03794876,0.8726336,0.003089127,0.07891095,0.0006605923],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.989557,0.00005587643,0.000754961,0.006888177,0.00001733986,0.000222741,0.00003363831,0.00002805874,0.002442235],"genre_scores_gemma":[0.9968786,0.0001811752,0.0002029618,0.0001842019,0.00007460813,0.00002970965,0.0001299939,0.000001386004,0.00231733],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1080519,"threshold_uncertainty_score":0.9174563,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00783841096732851,"score_gpt":0.2276365108732457,"score_spread":0.2197980999059171,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}