{"id":"W2024644208","doi":"10.1002/anie.201001008","title":"Isomerization of Triphenylmethoxyl: The Wieland Free‐Radical Rearrangement Revisited a Century Later","year":2010,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; University of Toronto; National Institute for Nanotechnology","funders":"","keywords":"Isomerization; Content (measure theory); Constant (computer programming); Reaction rate constant; Computer science; Scheme (mathematics); Chemistry; Photochemistry; Philosophy; Organic chemistry; Mathematics; Physics; Kinetics; Quantum mechanics; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008243211,0.0003933128,0.0004263934,0.0003914913,0.0004780461,0.0008719296,0.0005267436,0.001530759,0.003147456],"category_scores_gemma":[0.000956012,0.0003519281,0.0004072775,0.0003401458,0.001669556,0.004217664,0.0006932925,0.002504148,0.0006570178],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001786207,"about_ca_system_score_gemma":0.0005115672,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001211126,"about_ca_topic_score_gemma":0.0006798689,"domain_scores_codex":[0.9996823,0.00005171318,0.00001487179,0.0001330404,0.00005971225,0.00005835745],"domain_scores_gemma":[0.9996771,0.0001819083,0.0000416107,0.00004249822,0.00004204085,0.00001493213],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008867824,0.0001764504,0.0008161507,0.001444888,0.00009974724,0.0011526,0.000941812,0.00718162,0.256624,0.56884,0.005584028,0.156252],"study_design_scores_gemma":[0.0001038226,0.001333326,0.001877001,0.0002455326,0.00008083381,0.001278873,0.0005031064,0.01096866,0.5872368,0.09843621,0.2977491,0.0001867019],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.615263,0.2313233,0.0506298,0.02149371,0.003796927,0.0001055136,0.0004355644,0.0002607249,0.07669131],"genre_scores_gemma":[0.9227176,0.05366347,0.006482712,0.002001161,0.0005458124,0.00005119446,0.0001062429,0.0000797457,0.01435201],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003147456,"threshold_uncertainty_score":0.01295984,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009175822988074726,"score_gpt":0.255154389889151,"score_spread":0.2459785669010762,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}