{"id":"W2024882281","doi":"10.1021/ja004246f","title":"Interconversion of (<i>S</i>)-Glutamate and (2<i>S</i>,3<i>S</i>)-3-Methylaspartate:  A Distinctive B<sub>12</sub>-Dependent Carbon-Skeleton Rearrangement","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Porphyrin Metabolism and Disorders","field":"Biochemistry, Genetics and Molecular Biology","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Protonation; Stereochemistry; Ab initio; Substrate (aquarium); Computational chemistry; Photochemistry; Ion; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001025912,0.0003282101,0.0002170263,0.0001549679,0.0002637345,0.0002826298,0.0002696748,0.0002751345,0.001583726],"category_scores_gemma":[0.0004093388,0.0001437493,0.0002394091,0.0001633626,0.0002378166,0.0002996589,0.0002197274,0.0003485104,0.0002391773],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003886311,"about_ca_system_score_gemma":0.000222723,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006557872,"about_ca_topic_score_gemma":0.0005498637,"domain_scores_codex":[0.9999522,0.000007795194,0.000002531668,0.00001117243,0.00001161149,0.00001481852],"domain_scores_gemma":[0.9999148,0.00002809478,0.00002521068,0.00000906586,0.00001098899,0.0000118721],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007251502,0.00009226752,0.004131334,0.0002314044,0.00007184186,0.001303356,0.0003394835,0.01490509,0.9442373,0.01359025,0.0002604823,0.02011205],"study_design_scores_gemma":[0.00006533059,0.0004648069,0.005305481,0.0000116531,0.00004347849,0.0007211874,0.0001626141,0.04879059,0.9387747,0.004132206,0.001504511,0.00002335364],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919897,0.0003104454,0.005500911,0.00005014574,0.00001319451,0.00001168298,0.00004840614,0.0000593085,0.002016103],"genre_scores_gemma":[0.9981921,0.0001065601,0.001239419,0.000009134847,0.000001003182,0.00000500767,0.00003695396,0.00001133665,0.000398469],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001583726,"threshold_uncertainty_score":0.005298078,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004729341654987217,"score_gpt":0.2168857702419571,"score_spread":0.2121564285869699,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}