{"id":"W2024882281","doi":"10.1021/ja004246f","title":"Interconversion of (<i>S</i>)-Glutamate and (2<i>S</i>,3<i>S</i>)-3-Methylaspartate:  A Distinctive B<sub>12</sub>-Dependent Carbon-Skeleton Rearrangement","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Porphyrin Metabolism and Disorders","field":"Biochemistry, Genetics and Molecular Biology","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Protonation; Stereochemistry; Ab initio; Substrate (aquarium); Computational chemistry; Photochemistry; Ion; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003297813,0.0001865899,0.0003735756,0.00001895271,0.0000512156,0.00001336921,0.0003306963,0.00007251973,0.00000372893],"category_scores_gemma":[0.00009883388,0.0001321554,0.00039274,0.0001506205,0.0005145018,0.000008832994,0.0002769487,0.0002295766,4.315949e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003474346,"about_ca_system_score_gemma":0.00006009725,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006372562,"about_ca_topic_score_gemma":0.000005523929,"domain_scores_codex":[0.9987182,0.00009009337,0.0004036759,0.0002208858,0.0003199117,0.0002472408],"domain_scores_gemma":[0.9987195,0.00003171404,0.0007302856,0.0002623812,0.0001300886,0.0001260252],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003196322,0.0000999368,0.006759292,0.00001959448,0.0001564171,0.000002549315,0.0001556939,0.00001301165,0.9885116,0.000002035904,0.001715755,0.002244539],"study_design_scores_gemma":[0.0009193866,0.000209045,0.004991901,0.00003175424,0.0001178251,0.00006061671,0.0007652249,0.00002162383,0.9898013,0.0001107548,0.002813034,0.0001575135],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980289,0.0008540167,0.0001731946,0.0004971121,0.00015495,0.000101111,0.00001157246,0.000004054744,0.00017503],"genre_scores_gemma":[0.9954274,0.003372926,0.0003700654,0.0005978718,0.0001784139,0.000003040716,0.000003741042,0.00001878027,0.00002774495],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002601543,"threshold_uncertainty_score":0.5389143,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004729341654987217,"score_gpt":0.2168857702419571,"score_spread":0.2121564285869699,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}