{"id":"W2024886247","doi":"10.1021/jp057204s","title":"Solvation of the <i>N</i>-(1-Phenylethyl)-<i>N</i>‘-[3-(triethoxysilyl)propyl]-urea Chiral Stationary Phase in Mixed Alcohol/Water Solvents","year":2006,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Solvation; Alcohol; Urea; Phase (matter); Chemistry; Organic chemistry; Solvent","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003833388,0.0002910178,0.0004572895,0.00002607668,0.0001180727,0.00002084201,0.000784362,0.0001518635,0.0002578789],"category_scores_gemma":[0.00007123838,0.000159753,0.0005076234,0.0003289314,0.0004203438,0.0001670756,0.0001276192,0.0007972564,0.000003596928],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007371186,"about_ca_system_score_gemma":0.0000901519,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002257923,"about_ca_topic_score_gemma":0.000001180064,"domain_scores_codex":[0.9977345,0.00006181402,0.0008752784,0.000189149,0.000762174,0.0003770543],"domain_scores_gemma":[0.9983798,0.0002350279,0.0006241747,0.0004503347,0.0002154858,0.00009518558],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003090239,0.001115876,0.0005801315,0.0002360204,0.00008410518,0.000009863344,0.0002058205,0.0007890774,0.9958373,0.00007092969,0.0005431017,0.0002188015],"study_design_scores_gemma":[0.002150723,0.00003396147,0.0003877101,0.0001525117,0.0001747375,0.00004206551,0.0002349094,0.0009009917,0.9882302,0.007061752,0.0004347286,0.0001956864],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9932346,0.0001249065,0.0001216272,0.0003650432,0.00003477319,0.00005713549,0.00003904503,0.00001408531,0.006008782],"genre_scores_gemma":[0.9985417,0.00001199745,0.00005040343,0.00004771415,0.0006407065,0.000004171891,0.00004240393,0.00002619408,0.0006346978],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007607026,"threshold_uncertainty_score":0.651454,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008721786852931408,"score_gpt":0.2487585666015917,"score_spread":0.2400367797486603,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}