{"id":"W2024918719","doi":"10.1021/jo0301090","title":"Development of Novel Antioxidants:  Design, Synthesis, and Reactivity","year":2003,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":178,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University; University of Ottawa","funders":"","keywords":"Chemistry; DPPH; Bond-dissociation energy; Reactivity (psychology); Antioxidant; Semiquinone; Radical; Molecule; Dissociation (chemistry); Enthalpy; Double bond; Computational chemistry; Organic chemistry; Combinatorial chemistry; Redox; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000564321,0.0002710398,0.0004026458,0.0002295225,0.0002044742,0.0003644344,0.000394481,0.0003773585,0.0007487255],"category_scores_gemma":[0.0002643064,0.0001586397,0.0002123072,0.0001259688,0.0002483115,0.0005194455,0.0002136395,0.0004380746,0.0003339769],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003900563,"about_ca_system_score_gemma":0.0003583341,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001450251,"about_ca_topic_score_gemma":0.0003827264,"domain_scores_codex":[0.9998682,0.00002310093,0.0000145041,0.00002916725,0.00004898005,0.00001598317],"domain_scores_gemma":[0.9998435,0.00002974453,0.00004164041,0.0000137429,0.00004257629,0.0000288118],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000120953,0.000109512,0.0005946648,0.0007478277,0.00002845809,0.0001260815,0.00005210059,0.001716699,0.956055,0.002947073,0.0001698562,0.03733182],"study_design_scores_gemma":[0.00005701763,0.0008536865,0.0004701733,0.00002709785,0.00004635487,0.0003639534,0.00002205024,0.002146035,0.967571,0.0006237329,0.02780556,0.00001337676],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.825999,0.04571282,0.1217675,0.001142625,0.0002093744,0.0003268154,0.0003020039,0.0002518173,0.004288053],"genre_scores_gemma":[0.8158487,0.02590046,0.1523239,0.0003749237,0.0001037694,0.0002421647,0.000295539,0.00004148584,0.004868963],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007487255,"threshold_uncertainty_score":0.002984464,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02360091955402411,"score_gpt":0.2277917161047275,"score_spread":0.2041907965507034,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}