{"id":"W2024918719","doi":"10.1021/jo0301090","title":"Development of Novel Antioxidants:  Design, Synthesis, and Reactivity","year":2003,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":178,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University; University of Ottawa","funders":"","keywords":"Chemistry; DPPH; Bond-dissociation energy; Reactivity (psychology); Antioxidant; Semiquinone; Radical; Molecule; Dissociation (chemistry); Enthalpy; Double bond; Computational chemistry; Organic chemistry; Combinatorial chemistry; Redox; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009002747,0.0001448654,0.0002905557,0.00001362528,0.00008874407,0.00001311845,0.0002586574,0.00009820746,0.0008718474],"category_scores_gemma":[0.0006250327,0.00009924146,0.00005556431,0.00009255559,0.0001233585,0.00007116114,0.00003878676,0.0002707611,0.000001226865],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005094169,"about_ca_system_score_gemma":0.0002807198,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":9.245147e-7,"about_ca_topic_score_gemma":5.481446e-7,"domain_scores_codex":[0.9989152,0.000023263,0.0005034077,0.0000976868,0.000288016,0.0001724181],"domain_scores_gemma":[0.9987624,0.000301043,0.0005339914,0.0002133396,0.00009210114,0.00009715779],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003848716,0.0002096646,0.0002250647,0.0001455676,0.0000856863,0.000005229853,0.0001563067,0.000001509483,0.9977093,0.000005003669,0.0000559104,0.001362316],"study_design_scores_gemma":[0.0004755748,0.000005270878,0.000383887,0.0002413144,0.00006906088,0.0007494733,0.0003238256,0.00001020484,0.996517,0.00002914901,0.001082002,0.0001132058],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927425,0.0007362991,0.004932624,0.00005076172,0.00002552552,0.00001735711,0.000003049944,0.00000725907,0.001484568],"genre_scores_gemma":[0.9909968,0.0002868028,0.008501765,0.000009004536,0.00005307075,4.630141e-7,1.747305e-7,0.00001878507,0.0001331564],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003569141,"threshold_uncertainty_score":0.9546118,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02360091955402411,"score_gpt":0.2277917161047275,"score_spread":0.2041907965507034,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}