{"id":"W2025014476","doi":"10.1021/om8009377","title":"Synthesis and Characterization of Nitrile-Functionalized N-Heterocyclic Carbenes and Their Complexes of Silver(I) and Rhodium(I)","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Carbene; Chemistry; Nitrile; Tetrafluoroborate; Rhodium; Medicinal chemistry; Ligand (biochemistry); Alkylation; Reagent; Acetylacetone; Thiocyanate; Catalysis; Organic chemistry; Ionic liquid","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001419612,0.0002070985,0.0001907313,0.0001348946,0.00008694423,0.0002227049,0.0003668116,0.0003233896,0.0007687638],"category_scores_gemma":[0.0003160519,0.0001076222,0.0001136108,0.0001087602,0.0001111362,0.0001469096,0.0001207536,0.0002178973,0.0003067691],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002526459,"about_ca_system_score_gemma":0.0001637024,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008799173,"about_ca_topic_score_gemma":0.001903699,"domain_scores_codex":[0.999855,0.00001817424,0.00001210923,0.00003213821,0.00005947947,0.0000230112],"domain_scores_gemma":[0.9998388,0.00002730436,0.00004080189,0.00001881015,0.00003920431,0.00003502541],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002501663,0.000009616105,0.00006259518,0.00001854403,0.000001628448,0.00002565422,0.000006752265,0.00005706188,0.9990786,0.0000325055,0.00001204338,0.0006699913],"study_design_scores_gemma":[0.000006011111,0.0001128816,0.00125452,0.000002213453,0.000004590569,0.0001032961,0.000006514144,0.000465423,0.9971805,0.000009085539,0.0008509133,0.000004034769],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906199,0.001176457,0.005176608,0.00003489821,0.00001048576,0.00007245814,0.0002779428,0.00006479646,0.00256647],"genre_scores_gemma":[0.9871613,0.0005759008,0.008764421,0.00002650503,0.000005009648,0.00005652804,0.0006048237,0.00002714478,0.002778298],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008799173,"threshold_uncertainty_score":0.002571702,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009702013880282639,"score_gpt":0.206428792403994,"score_spread":0.1967267785237114,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}