{"id":"W2025068491","doi":"10.1002/chin.200006107","title":"ChemInform Abstract: Synthesis, Structure and AM1 Conformational Study of [3]Paracyclo[3](1,3)indolophane, a Novel Chiral Cyclophane.","year":2000,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Cyclophane; Stereochemistry; Combinatorial chemistry; Organic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001614235,0.0004164147,0.0005847387,0.0000760654,0.0001679725,0.0000957239,0.0004908811,0.0002277062,0.02528303],"category_scores_gemma":[0.0001347731,0.0003519383,0.0001137048,0.0001222828,0.0001691602,0.0005228037,0.0001118847,0.0002629288,0.0000306589],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006593895,"about_ca_system_score_gemma":0.00008715076,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008168987,"about_ca_topic_score_gemma":0.00001035253,"domain_scores_codex":[0.9977642,1.322709e-7,0.0009554263,0.0002933528,0.0005698082,0.0004170686],"domain_scores_gemma":[0.9985238,0.0002754144,0.0003580295,0.0005704744,0.0000917413,0.000180582],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004381285,0.0006295095,0.0005213523,0.0008823895,0.0003068477,0.00000536622,0.006131694,0.000004433829,0.01882697,0.00006699612,0.001982952,0.9702033],"study_design_scores_gemma":[0.003746916,0.0001465122,0.01558985,0.0003796541,0.000176223,0.0002826749,0.005845621,0.0001744645,0.9322547,0.0002860173,0.0399621,0.00115524],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5450945,0.00008070203,1.557232e-8,0.00002229194,0.00002576883,0.0001199175,0.00008024662,0.0000470325,0.4545295],"genre_scores_gemma":[0.9851142,0.00005115418,0.00007919015,0.00005296949,0.0001371139,0.00005342675,0.00005998692,0.00003046428,0.01442148],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.9690481,"threshold_uncertainty_score":0.9998932,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01406764925011179,"score_gpt":0.2224032508597661,"score_spread":0.2083356016096543,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}