{"id":"W2025207972","doi":"10.1002/anie.201403714","title":"Mechanistic Study of the Role of Primary Amines in Precursor Conversions to Semiconductor Nanocrystals at Low Temperature","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Quantum Dots Synthesis And Properties","field":"Materials Science","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"National Natural Science Foundation of China","keywords":"Nanocrystal; Phosphine; Amine gas treating; Primary (astronomy); Alkyl; Semiconductor; Particle (ecology); Chemistry; Materials science; Chemical engineering; Nanotechnology; Combinatorial chemistry; Organic chemistry; Catalysis; Optoelectronics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002073346,0.00008985864,0.0001669824,0.00005967777,0.00004358456,0.00001561406,0.0002758607,0.00004783344,0.0004081251],"category_scores_gemma":[0.0002236201,0.00006120773,0.00003979066,0.00008403646,0.00004477946,0.0001220345,0.0001273989,0.00004771197,0.00001217976],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008586807,"about_ca_system_score_gemma":0.00002019789,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000940631,"about_ca_topic_score_gemma":0.00007235415,"domain_scores_codex":[0.9991027,0.00005024494,0.0002563086,0.000173848,0.0003255253,0.00009142137],"domain_scores_gemma":[0.9993849,0.0001146258,0.0001486675,0.0001655842,0.0001593825,0.00002679051],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007320513,0.0001853566,0.0007415666,0.00002928613,0.000008010819,2.263396e-7,0.001035417,0.00001788319,0.9967279,0.0001269693,0.001004074,0.00005010318],"study_design_scores_gemma":[0.0002714419,0.00009303637,0.002057318,0.0001515868,0.00001086524,0.000001835606,0.0006055144,0.00002397593,0.9955719,0.0002591838,0.0008821318,0.00007125507],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978482,0.00004679617,0.000007648976,0.0001721739,0.0007669767,0.0002262812,0.0001180331,0.000009733996,0.0008041633],"genre_scores_gemma":[0.9993062,0.000006852936,0.00004973411,0.00008572761,0.0001772074,0.00003702017,0.00002289352,0.00000782385,0.0003065408],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001458007,"threshold_uncertainty_score":0.4468683,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01076060062992051,"score_gpt":0.2193528754579892,"score_spread":0.2085922748280687,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}