{"id":"W2025249700","doi":"10.1139/v06-090","title":"1,4,8,11-Tetra[2-aryl-1-diazenyl]-1,4,8,11-tetraazacyclotetradecanes — Synthesis, characterization, and X-ray crystallography of the first tetrakistriazenes to be reported","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Chemistry; Triazene; Cyclam; Tetra; Aryl; Molecule; Mass spectrometry; Crystallography; Salt (chemistry); X-ray; Proton NMR; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Stereochemistry; Metal; Alkyl; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006364224,0.0002308115,0.0001833474,0.0001684885,0.0001700004,0.0002070582,0.0002142014,0.0001766262,0.001981977],"category_scores_gemma":[0.0001180658,0.0001096566,0.00009263775,0.0002945204,0.0001908315,0.0001928502,0.0001187573,0.0004061053,0.0006568212],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004046554,"about_ca_system_score_gemma":0.0003927168,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009826205,"about_ca_topic_score_gemma":0.002706179,"domain_scores_codex":[0.99993,0.000006481204,0.000005944799,0.00001597597,0.00002742508,0.00001417039],"domain_scores_gemma":[0.9999619,0.000004032941,0.00000953291,0.0000051906,0.00001111646,0.000008282699],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006542313,0.00002477769,0.0001107495,0.00007668327,0.000005322275,0.00006443414,0.0000263169,0.0002412289,0.9952661,0.0004993579,0.0001182723,0.003501414],"study_design_scores_gemma":[0.00002569385,0.0002481723,0.001184851,0.000006725448,0.000006077199,0.0003227585,0.00003107518,0.0003435049,0.9831217,0.00009250522,0.0146089,0.000008079424],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9702534,0.006823056,0.009171341,0.0002648085,0.00009240879,0.0001447549,0.0008854339,0.0001811586,0.01218365],"genre_scores_gemma":[0.9676972,0.006696659,0.008648654,0.0001131703,0.00001630763,0.0001565532,0.001585045,0.00003769026,0.01504876],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001981977,"threshold_uncertainty_score":0.006630361,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008269925240454253,"score_gpt":0.1888308187979497,"score_spread":0.1805608935574955,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}