{"id":"W2025309236","doi":"10.1016/s0009-2509(00)00418-8","title":"Solvent effects in chiral ligand exchange systems","year":2001,"lang":"en","type":"article","venue":"Chemical Engineering Science","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"","keywords":"Ligand (biochemistry); Solvent; Chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006477979,0.0004265188,0.000678473,0.0003497862,0.0007221688,0.0008642795,0.000476467,0.0003957505,0.005100885],"category_scores_gemma":[0.001593274,0.0003241536,0.0001940503,0.0003154522,0.000721926,0.00119288,0.0007273306,0.0006932667,0.0005694373],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004170074,"about_ca_system_score_gemma":0.0003068115,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001085057,"about_ca_topic_score_gemma":0.001186465,"domain_scores_codex":[0.9997162,0.00008956373,0.00001533731,0.00004097649,0.00006912821,0.000068706],"domain_scores_gemma":[0.9993126,0.0004983501,0.0000609758,0.00003209744,0.00004975343,0.0000461004],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003601989,0.000279568,0.001096403,0.001486327,0.000115151,0.001166425,0.0008209333,0.02843546,0.8356113,0.08023372,0.004764764,0.04238804],"study_design_scores_gemma":[0.0003326341,0.0006611131,0.001118323,0.00006272401,0.0001216332,0.0002375497,0.0002810363,0.07246894,0.9014368,0.01321159,0.009955981,0.0001116883],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9616756,0.005382753,0.01784058,0.0009639187,0.0002241725,0.00003706118,0.000128263,0.0005386147,0.01320905],"genre_scores_gemma":[0.9934761,0.001913866,0.001330418,0.0002016788,0.00006808208,0.00002824712,0.00009204743,0.00008515302,0.002804381],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005100885,"threshold_uncertainty_score":0.01706415,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005809871037897357,"score_gpt":0.2058416399478005,"score_spread":0.2000317689099032,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}