{"id":"W2025532681","doi":"10.1021/ja0556023","title":"Unprecedented Coordination Modes and Demetalation Pathways for Unbridged Polyenyl Ligands. Ruthenium η,η<sup>4</sup>-Cycloheptadienyl Complexes from Allyl/Alkyne Cycloaddition","year":2005,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Cycloheptatriene; Alkyne; Hydride; Ruthenium; Isomerization; Hexamethylbenzene; Cycloaddition; Medicinal chemistry; Propyne; Cationic polymerization; Phenylacetylene; Stereochemistry; Regioselectivity; Photochemistry; Polymer chemistry; Metal; Organic chemistry; Catalysis; Benzene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007969337,0.0003299419,0.00009584415,0.0001130984,0.0001481542,0.0003663705,0.0003683829,0.0001984003,0.00291874],"category_scores_gemma":[0.0001836264,0.0001698109,0.0000805093,0.0001584033,0.0001431429,0.0003524875,0.0003603873,0.0003474939,0.0009368958],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005008739,"about_ca_system_score_gemma":0.0001724186,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004822784,"about_ca_topic_score_gemma":0.0008688295,"domain_scores_codex":[0.9999228,0.00001109567,0.000005377928,0.00002283555,0.00001667352,0.00002124496],"domain_scores_gemma":[0.999939,0.00001140811,0.00002047112,0.00001043108,0.000006668639,0.00001196515],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002052739,0.00004115254,0.0002747922,0.0001109357,0.00001051335,0.0001760042,0.0001346346,0.001307226,0.9814029,0.00316095,0.0004436509,0.01273184],"study_design_scores_gemma":[0.00002376257,0.0001546848,0.00063392,0.000005059811,0.00000600699,0.0001371297,0.00002519795,0.001252208,0.9869021,0.0001807202,0.01066922,0.000009995638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9702873,0.001196893,0.008659068,0.0001317978,0.00003620605,0.00006974707,0.0003994558,0.0003125727,0.01890697],"genre_scores_gemma":[0.9892085,0.0005699796,0.003832866,0.00003595,0.000005538432,0.00005171278,0.0002669457,0.00006256811,0.00596592],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00291874,"threshold_uncertainty_score":0.009764194,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01234695929132714,"score_gpt":0.2235555768199858,"score_spread":0.2112086175286587,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}