{"id":"W2025688917","doi":"10.1039/b612306f","title":"Stoichiometric and catalytic activation of P–H and P–P bonds","year":2008,"lang":"en","type":"review","venue":"Chemical Society Reviews","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":162,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Stoichiometry; Catalysis; Chemistry; Reactivity (psychology); Organometallic chemistry; Transition metal; Phosphorus; Combinatorial chemistry; Nanotechnology; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003833979,0.0005921577,0.002990986,0.00003685273,0.00005605033,0.00001784259,0.0003249029,0.0008251299,0.0002596515],"category_scores_gemma":[0.001568281,0.0004742471,0.0007869502,0.0007707421,0.0003866715,0.000070402,0.0003042624,0.0006782347,0.00001042241],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002014234,"about_ca_system_score_gemma":0.0001268185,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003659037,"about_ca_topic_score_gemma":1.027428e-8,"domain_scores_codex":[0.9975207,0.00005095856,0.001166169,0.0007097787,0.0002592904,0.0002930542],"domain_scores_gemma":[0.9972791,0.000885751,0.0009043225,0.0006912067,0.00004373349,0.0001958563],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[8.101769e-7,0.00003700334,0.000001433169,0.07094748,0.0001047348,4.173006e-7,0.0000523651,1.049861e-9,0.01078611,0.000002753764,0.00229892,0.915768],"study_design_scores_gemma":[0.0002000704,0.000003722266,1.182825e-7,0.009572011,0.000576211,0.0001772094,0.00001097564,0.000004276331,0.02282362,0.00001419186,0.9662153,0.000402291],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0001549103,0.9977286,0.00002622196,0.00001486525,0.00001637882,0.0002832367,0.00002913299,0.00003765721,0.001709006],"genre_scores_gemma":[0.000007485313,0.9945849,0.004391418,0.00002349028,0.000201545,0.0000758875,0.0001238419,0.00007373392,0.0005177511],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9639164,"threshold_uncertainty_score":0.9997709,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08079722349906718,"score_gpt":0.3566837546268294,"score_spread":0.2758865311277623,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}