{"id":"W2025709115","doi":"10.1016/j.jpba.2008.10.038","title":"A novel derivatization-free method of formaldehyde and propylene glycol determination in hydrogels by liquid chromatography with refractometric detection","year":2008,"lang":"en","type":"article","venue":"Journal of Pharmaceutical and Biomedical Analysis","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"Collège de Maisonneuve","funders":"","keywords":"Chemistry; Derivatization; Formaldehyde; Chromatography; Ethylene glycol; Detection limit; Polyvinyl alcohol; High-performance liquid chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003834244,0.0001875688,0.000577692,0.0008808689,0.00007994958,0.00001508787,0.0001754228,0.0001879079,0.0001529889],"category_scores_gemma":[0.0001876217,0.0001297968,0.0002152902,0.003635783,0.0005392261,0.0002089335,0.00006011028,0.0003462629,1.093617e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002749974,"about_ca_system_score_gemma":0.00003898681,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001875276,"about_ca_topic_score_gemma":0.000004240349,"domain_scores_codex":[0.9980667,0.0000354503,0.0007938274,0.0002262073,0.0006491817,0.0002286474],"domain_scores_gemma":[0.9986514,0.0002479367,0.0004326967,0.0001235472,0.000173305,0.0003711062],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007736297,0.0009388953,0.02345658,0.0004256833,0.00122506,0.00006622969,0.0001309879,0.000007926971,0.9628859,0.000007900805,0.00001737968,0.01006388],"study_design_scores_gemma":[0.004392245,0.0006226929,0.003236827,0.0001434637,0.002531264,0.001137309,0.0001834682,0.02317988,0.9628312,0.00009486119,0.001308018,0.0003387561],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8753239,0.0005831405,0.1237326,0.000214047,0.00000619511,0.00003820784,0.00002221828,0.000009136432,0.00007059718],"genre_scores_gemma":[0.9926447,0.0007125975,0.00651518,0.0000462189,0.00004677079,0.000004349642,0.00001034569,0.00000894035,0.0000109547],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1173208,"threshold_uncertainty_score":0.529296,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01315524356183816,"score_gpt":0.2834211424093578,"score_spread":0.2702658988475196,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}