{"id":"W2025774115","doi":"10.1021/jo301408j","title":"Oxidative <i>ipso</i>-Rearrangement Performed by a Hypervalent Iodine Reagent and Its Application","year":2012,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hypervalent molecule; Chemistry; Reagent; Iodine; Aryl; Oxidative phosphorylation; Silylation; Combinatorial chemistry; Organic chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001783104,0.000493126,0.0001464832,0.000215207,0.000151187,0.000271053,0.0005011164,0.0003485232,0.001832703],"category_scores_gemma":[0.0001493761,0.0001869516,0.0002936076,0.0001585323,0.0005411194,0.0004180161,0.0004001617,0.0007567356,0.0004517096],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003351226,"about_ca_system_score_gemma":0.0002647437,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004967703,"about_ca_topic_score_gemma":0.0005966697,"domain_scores_codex":[0.9998811,0.00001407885,0.000008089367,0.00002606789,0.00003450625,0.0000361589],"domain_scores_gemma":[0.9999369,0.00001101685,0.00002301028,0.000008960268,0.000009971537,0.00001005766],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000673317,0.00001535262,0.00010257,0.0001282268,0.000009946876,0.0001920542,0.00006256773,0.0003001461,0.9907225,0.002027583,0.00009027153,0.006281412],"study_design_scores_gemma":[0.000007213109,0.0001505396,0.0003451092,0.000006062317,0.00001003957,0.0002210307,0.00002059882,0.0002221094,0.9956281,0.0001152503,0.003264923,0.000008866838],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.916963,0.007056423,0.0414485,0.0003647751,0.0001219763,0.0001685123,0.0002952423,0.0002812496,0.03330019],"genre_scores_gemma":[0.9894866,0.001585259,0.005160468,0.00004555595,0.000009931805,0.00003496049,0.0001153289,0.0000205588,0.003541406],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001832703,"threshold_uncertainty_score":0.006130993,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01304421950073842,"score_gpt":0.2333208140438037,"score_spread":0.2202765945430653,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}