{"id":"W2025783141","doi":"10.1021/ja045080b","title":"Anion-Templated Assembly of a [2]Catenane","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":200,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Catenane; Chemistry; Catenation; Ion; Yield (engineering); Selectivity; Chloride; Combinatorial chemistry; Organic chemistry; Molecule; Catalysis; Biochemistry; DNA","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002243716,0.0003718313,0.0002743639,0.0001740001,0.000204809,0.0004918613,0.00046571,0.0005139731,0.001428198],"category_scores_gemma":[0.0003024392,0.0002476087,0.0001980203,0.0001658285,0.0001899741,0.0004133056,0.0003399625,0.0005963092,0.000721776],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002635371,"about_ca_system_score_gemma":0.0002214793,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000417548,"about_ca_topic_score_gemma":0.000976508,"domain_scores_codex":[0.9997807,0.00004004761,0.00002073658,0.00005571541,0.00005230475,0.0000504942],"domain_scores_gemma":[0.9998916,0.0000150347,0.00002444425,0.00001714555,0.00002730469,0.00002440828],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003312801,0.00002029494,0.0000310873,0.00004679655,0.000003491493,0.0001006829,0.00003276726,0.0004240656,0.9968148,0.0006625706,0.00007343261,0.001756976],"study_design_scores_gemma":[0.00001288684,0.0001663693,0.0001578946,0.000004385455,0.000003900255,0.0001306457,0.00001135512,0.001721675,0.9913868,0.0001058618,0.006282532,0.00001558851],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9476252,0.001869153,0.03674045,0.000203133,0.0002856285,0.0002401357,0.0003193628,0.0006672511,0.0120498],"genre_scores_gemma":[0.9531108,0.0009649329,0.03401275,0.0002220216,0.00004129573,0.0001144333,0.000413935,0.0000827918,0.01103717],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001428198,"threshold_uncertainty_score":0.004777789,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008009724995958294,"score_gpt":0.2345400143803033,"score_spread":0.226530289384345,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}