{"id":"W2025894930","doi":"10.1021/jp012419x","title":"Nucleation and Growth of Hydrates on Ice Surfaces:  New Insights from <sup>129</sup>Xe NMR Experiments with Hyperpolarized Xenon","year":2001,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Methane Hydrates and Related Phenomena","field":"Environmental Science","cited_by":149,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Nucleation; Hydrate; Clathrate hydrate; Xenon; Chemistry; Induction period; Desorption; Diffusion; Thermodynamics; Free induction decay; Surface diffusion; Adsorption; Physical chemistry; Chemical physics; Analytical Chemistry (journal); Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001168972,0.0002458772,0.0002591904,0.0001493148,0.0001354829,0.0002716398,0.0002704689,0.0002997023,0.0004427497],"category_scores_gemma":[0.0001050361,0.0002029129,0.0001849259,0.0001064351,0.0004297344,0.0004818715,0.0002278555,0.0005059065,0.0001394236],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002047869,"about_ca_system_score_gemma":0.00005718083,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006235125,"about_ca_topic_score_gemma":0.0007925387,"domain_scores_codex":[0.999946,0.000007400086,0.000002288929,0.00001171581,0.00002033465,0.00001225105],"domain_scores_gemma":[0.9999377,0.00003735004,0.000007925217,0.000004140777,0.000007231526,0.000005668333],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008144612,0.0000119192,0.0003503742,0.0001452879,0.000005409658,0.0002346681,0.0001315816,0.0002478709,0.995551,0.000665631,0.00006396419,0.002510822],"study_design_scores_gemma":[0.00001038323,0.0001593314,0.008933892,0.00001971986,0.00001466982,0.0008162006,0.0002630052,0.005016879,0.9800982,0.0009029745,0.0037459,0.00001869407],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9815825,0.00622113,0.006908739,0.0002188472,0.00002440503,0.00002058388,0.0002047384,0.00005805143,0.004760916],"genre_scores_gemma":[0.9832578,0.007950296,0.006660021,0.00008799729,0.00005384191,0.00001884992,0.0003620221,0.00003431352,0.00157487],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006235125,"threshold_uncertainty_score":0.001485825,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008709946336270374,"score_gpt":0.2085541210262602,"score_spread":0.1998441746899898,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}