{"id":"W2025917224","doi":"10.1002/marc.200700750","title":"TEMPO‐Mediated Emulsion Polymerization","year":2008,"lang":"en","type":"article","venue":"Macromolecular Rapid Communications","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Xerox (Canada); Queen's University","funders":"","keywords":"Miniemulsion; Polymerization; Emulsion polymerization; Polymer chemistry; Monomer; Radical polymerization; Chain-growth polymerization; Materials science; Chain transfer; Emulsion; Bulk polymerization; Chemistry; Chemical engineering; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002104207,0.0004082519,0.0002012615,0.0003124064,0.0001722896,0.0002923727,0.000333113,0.0002989715,0.00336426],"category_scores_gemma":[0.0001880504,0.0002047131,0.0001845009,0.0001723502,0.0001841684,0.0003822396,0.0003221928,0.001071952,0.0009873421],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002147077,"about_ca_system_score_gemma":0.0002129095,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002318504,"about_ca_topic_score_gemma":0.0002128512,"domain_scores_codex":[0.9998871,0.000009882072,0.000007537583,0.00003383976,0.00003514334,0.00002643435],"domain_scores_gemma":[0.9999207,0.00001936766,0.00002086263,0.000008808532,0.0000141526,0.00001608383],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002676302,0.00001530045,0.00001507373,0.00006365272,0.000004148269,0.00007344921,0.0000192115,0.00007730509,0.9957556,0.0005703758,0.0002417058,0.003137553],"study_design_scores_gemma":[0.00001484336,0.00006351063,0.00008883125,0.000003789423,0.000003223872,0.00009237992,0.000002437478,0.000688935,0.9947045,0.00008040993,0.004252842,0.0000043121],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.803135,0.005341227,0.1477381,0.0007388688,0.0006336494,0.0003974953,0.0008208625,0.00328768,0.03790721],"genre_scores_gemma":[0.9271359,0.003550739,0.03964851,0.0002848593,0.00007747424,0.0001649299,0.0005897703,0.0002787378,0.02826903],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00336426,"threshold_uncertainty_score":0.01125461,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02276234870639001,"score_gpt":0.2390914087158967,"score_spread":0.2163290600095067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}