{"id":"W2025917224","doi":"10.1002/marc.200700750","title":"TEMPO‐Mediated Emulsion Polymerization","year":2008,"lang":"en","type":"article","venue":"Macromolecular Rapid Communications","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Xerox (Canada); Queen's University","funders":"","keywords":"Miniemulsion; Polymerization; Emulsion polymerization; Polymer chemistry; Monomer; Radical polymerization; Chain-growth polymerization; Materials science; Chain transfer; Emulsion; Bulk polymerization; Chemistry; Chemical engineering; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000042984,0.0001860276,0.0001799969,0.00008112741,0.0006250328,0.00002721302,0.0007435989,0.0001162753,0.0009985572],"category_scores_gemma":[0.0000854185,0.0002027039,0.0001005022,0.0003055822,0.0001933992,0.0001708902,0.0002348069,0.0001901138,0.0001391371],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004109749,"about_ca_system_score_gemma":0.00003524427,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000255728,"about_ca_topic_score_gemma":0.000002749792,"domain_scores_codex":[0.9988744,0.00007806035,0.0003539562,0.0002494433,0.0002108599,0.0002332453],"domain_scores_gemma":[0.9977038,0.00009660936,0.0001887009,0.00185167,0.00007796032,0.00008126653],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009935092,0.0001680884,0.0006673688,0.00001147981,0.00003024347,0.000007113742,0.0003056107,0.00000331506,0.983301,0.0005453708,0.00007073128,0.01487975],"study_design_scores_gemma":[0.0005853524,0.00002037822,0.001395989,0.00006051943,0.00003773552,0.00009113659,0.0001191872,0.002649495,0.8670146,0.00009312262,0.1274617,0.0004708084],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7836526,0.01939588,0.05730432,0.005406636,0.0002849188,0.0004973396,0.0003346197,0.001682292,0.1314414],"genre_scores_gemma":[0.9930663,0.002545182,0.001740184,0.000274131,0.00003370497,0.00007788142,0.001486759,0.00005133975,0.0007245411],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2094137,"threshold_uncertainty_score":0.9999146,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02276234870639001,"score_gpt":0.2390914087158967,"score_spread":0.2163290600095067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}