{"id":"W2025927529","doi":"10.1007/s00216-011-5092-2","title":"Study of alkyl phosphates in industrial petroleum mixtures by comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry","year":2011,"lang":"en","type":"article","venue":"Analytical and Bioanalytical Chemistry","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"Imperial Oil (Canada); University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Alkyl; Chemistry; Mass spectrometry; Gas chromatography; Chromatography; Petroleum; Gas chromatography–mass spectrometry; Phosphate; Refinery; Analyte; Contamination; Mass spectrum; Environmental chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002618353,0.0006434547,0.0002643197,0.001139981,0.0006189573,0.0005463674,0.0004220777,0.0006533222,0.0005247977],"category_scores_gemma":[0.0004777889,0.0002845462,0.0002879781,0.0006036878,0.0004327344,0.001002704,0.0005284147,0.000654394,0.0002198297],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004523532,"about_ca_system_score_gemma":0.0007759021,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004634685,"about_ca_topic_score_gemma":0.004285776,"domain_scores_codex":[0.9996428,0.00002634555,0.00001739861,0.0000932509,0.0001707401,0.00004939824],"domain_scores_gemma":[0.9998127,0.00004716757,0.00004099827,0.000008985775,0.00006775826,0.00002237753],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000417206,0.00006207793,0.004587693,0.00008364444,0.0000343736,0.0001474145,0.00008988882,0.0003709168,0.9842669,0.0001930354,0.0000918941,0.009654848],"study_design_scores_gemma":[0.00001476808,0.0002073198,0.01483056,0.000009915681,0.00003410348,0.0004429497,0.0001106852,0.005523697,0.9766197,0.0001942808,0.001982005,0.00003010597],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9746517,0.004483226,0.01695604,0.0001436247,0.00003880177,0.00006012785,0.000759337,0.0002037473,0.002703458],"genre_scores_gemma":[0.9873801,0.002194318,0.008510067,0.00008435076,0.00002653835,0.00003615544,0.0004675041,0.00003200855,0.001269021],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004634685,"threshold_uncertainty_score":0.009215415,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01969721698949762,"score_gpt":0.2339603834756107,"score_spread":0.2142631664861131,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}