{"id":"W2025976759","doi":"10.1021/op000209x","title":"From Adenosine to 3‘-Deoxyadenosine:  Development and Scale Up","year":2000,"lang":"en","type":"article","venue":"Organic Process Research & Development","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Energy","funders":"","keywords":"Deoxyadenosine; Adenosine; Scale (ratio); Chemistry; Biochemistry; Geography; Cartography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.000528305,0.0003656606,0.0003705315,0.0001325405,0.0006034451,0.0002380241,0.0006986149,0.000227223,0.02655849],"category_scores_gemma":[0.0002109978,0.0003585039,0.00003039963,0.0007271529,0.0001307991,0.0001592396,0.0003117119,0.0005294963,0.001345793],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004723358,"about_ca_system_score_gemma":0.001065645,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004134268,"about_ca_topic_score_gemma":0.00004417218,"domain_scores_codex":[0.9962065,0.00003450071,0.0005566663,0.0009761698,0.001254901,0.000971327],"domain_scores_gemma":[0.998351,0.000165823,0.00004767536,0.0004765354,0.0002910485,0.0006678526],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002293116,0.0002615902,0.001115203,0.0004074429,0.0001368485,0.00005853819,0.01693916,0.000002319445,0.813105,0.000003308692,0.004667033,0.1630742],"study_design_scores_gemma":[0.000403136,0.000008194409,0.001214626,0.0002657199,0.000008086799,0.00001438426,0.001199947,0.000006838996,0.89659,0.0001191895,0.09972813,0.0004417282],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9861147,0.0005759337,0.00002278456,0.0009110466,0.00003658804,0.0001702123,0.00001582947,0.0001464192,0.01200652],"genre_scores_gemma":[0.9725891,0.0001724668,0.002359874,0.0001037099,0.0002449427,0.0002437663,0.00009437629,0.00007667654,0.02411508],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1626325,"threshold_uncertainty_score":0.9998867,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02826983793551011,"score_gpt":0.3052350135551918,"score_spread":0.2769651756196817,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}