{"id":"W2026056466","doi":"10.1021/la9028996","title":"Molecular Pockets Derived from Cholic Acid as Chemosensors for Metal Ions","year":2009,"lang":"en","type":"article","venue":"Langmuir","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Trimer; Pyrene; Metal ions in aqueous solution; Cholic acid; Photochemistry; Metal; Porphyrin; Molecule; Quenching (fluorescence); Fluorescence; Inorganic chemistry; Organic chemistry; Dimer; Bile acid","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00003039334,0.0001657172,0.0001865823,0.00003561995,0.0001028047,0.00003587228,0.000131121,0.000153128,0.0005229021],"category_scores_gemma":[0.00006638451,0.0001628108,0.000191014,0.00008199997,0.000018225,0.00004614127,0.00001687612,0.0001228763,0.0001002811],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002739399,"about_ca_system_score_gemma":0.00001155613,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004637735,"about_ca_topic_score_gemma":0.000004827477,"domain_scores_codex":[0.9991292,0.00001336788,0.000159642,0.0002977765,0.0001547069,0.0002453151],"domain_scores_gemma":[0.9994992,0.00001625019,0.00006577743,0.0002866126,0.00004385631,0.00008829244],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003621119,0.00004442025,0.00001124949,0.000007072185,0.0000422031,0.00002338273,0.0001152513,0.000007199372,0.9933046,0.0001643834,0.0003026888,0.005941314],"study_design_scores_gemma":[0.0006306293,0.00003619836,0.0007812323,0.00001000911,0.0000537439,0.00001577134,0.00005914441,0.0002854461,0.9779861,0.0009280926,0.01901394,0.0001996628],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9884388,0.0002631133,0.0006651863,0.0006297091,0.00006438484,0.0000929177,0.00004655215,0.0001529952,0.009646364],"genre_scores_gemma":[0.9968861,0.000008889502,0.0009878462,0.000795405,0.0001930235,0.00001948389,0.0001481841,0.00002756815,0.0009335238],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01871125,"threshold_uncertainty_score":0.6639233,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01000763433380324,"score_gpt":0.2441346794932504,"score_spread":0.2341270451594472,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}