{"id":"W2026056466","doi":"10.1021/la9028996","title":"Molecular Pockets Derived from Cholic Acid as Chemosensors for Metal Ions","year":2009,"lang":"en","type":"article","venue":"Langmuir","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Trimer; Pyrene; Metal ions in aqueous solution; Cholic acid; Photochemistry; Metal; Porphyrin; Molecule; Quenching (fluorescence); Fluorescence; Inorganic chemistry; Organic chemistry; Dimer; Bile acid","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001726576,0.0002690348,0.0003904527,0.0001714232,0.0001398846,0.0002774735,0.0003194815,0.0004356154,0.0005467609],"category_scores_gemma":[0.0003760197,0.0001786142,0.0001969751,0.0001447094,0.0002753503,0.0003068975,0.0004014303,0.0004259246,0.0002993528],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002759276,"about_ca_system_score_gemma":0.0001383418,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004655758,"about_ca_topic_score_gemma":0.0004902151,"domain_scores_codex":[0.9998647,0.00002327942,0.000009949264,0.00003085578,0.00003024385,0.00004099857],"domain_scores_gemma":[0.9998052,0.00004099647,0.00004932412,0.00002527763,0.0000217801,0.00005742383],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000592245,0.000004630688,0.00004165728,0.00001847174,0.000001751866,0.00001999337,0.000008419236,0.00004242327,0.9992006,0.00002962913,0.000007462701,0.0005657197],"study_design_scores_gemma":[0.00001313197,0.0001256833,0.0005592947,0.000002994755,0.000008528905,0.0001220877,0.00001216395,0.0005312038,0.997886,0.00002172153,0.0007121717,0.000005032385],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9928711,0.001120789,0.005216883,0.00006882376,0.00001282062,0.00003530009,0.00009494481,0.0001439448,0.0004354589],"genre_scores_gemma":[0.9910766,0.000521204,0.007305178,0.00005145924,0.000006145719,0.00002817519,0.0001667919,0.00002221138,0.0008221285],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005467609,"threshold_uncertainty_score":0.002002001,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01000763433380324,"score_gpt":0.2441346794932504,"score_spread":0.2341270451594472,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}