{"id":"W2026201481","doi":"10.1021/ja046389y","title":"Synthesis of Postulated Molecular Probes:  Stereoselective Free-Radical-Mediated <i>C</i>-Glycosylation in Tandem with Hydrogen Transfer","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Université de Montréal; Montreal Clinical Research Institute","funders":"","keywords":"Chemistry; Tandem; Stereocenter; Stereoselectivity; Anomer; Glycosylation; Radical; Stereochemistry; Transition state; Selectivity; Cascade reaction; Free-radical reaction; Organic chemistry; Catalysis; Enantioselective synthesis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002036587,0.0004084467,0.0002000365,0.0001156776,0.0001292701,0.0003080915,0.0004176234,0.0004461844,0.001405129],"category_scores_gemma":[0.000164032,0.0001469757,0.0002127739,0.0000942314,0.0002503989,0.000429975,0.0002147186,0.0006406424,0.0005355275],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002327022,"about_ca_system_score_gemma":0.0002388187,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001151652,"about_ca_topic_score_gemma":0.0001780929,"domain_scores_codex":[0.99994,0.00001244456,0.000002996996,0.0000159485,0.00001082189,0.00001778791],"domain_scores_gemma":[0.999929,0.00001437409,0.0000242221,0.00001025916,0.000007995551,0.00001416732],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009234923,0.00004551308,0.0001106047,0.00008152239,0.000008653909,0.0001532641,0.00005228317,0.0002946783,0.9882292,0.002498739,0.0001416784,0.008291584],"study_design_scores_gemma":[0.00001601378,0.0002478129,0.0001219702,0.000002776169,0.000009420875,0.0001488522,0.000008227737,0.0002664111,0.9959065,0.0001945808,0.003070512,0.000006941671],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9111767,0.003275043,0.0724741,0.0004258381,0.0002248485,0.0003601658,0.0005479503,0.0004697598,0.01104563],"genre_scores_gemma":[0.9589286,0.001625413,0.03435422,0.0001432797,0.00003584361,0.0001200736,0.000314879,0.00003274416,0.004444881],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001405129,"threshold_uncertainty_score":0.004700601,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004775940313829691,"score_gpt":0.1973304611967186,"score_spread":0.1925545208828889,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}