{"id":"W2026481024","doi":"10.1021/ol027236n","title":"Increased Felkin−Anh Selectivity Using AlMe<sub>3</sub>in the Addition of Vinyllithiums to α-Chiral Aldehydes:  Do “Ate” Complexes Play Any Role?","year":2002,"lang":"en","type":"article","venue":"Organic Letters","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Methyllithium; Aldehyde; Selectivity; Medicinal chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002490318,0.0002891143,0.0002838777,0.0001456348,0.0001285425,0.0003527122,0.0003627832,0.0003814986,0.002170858],"category_scores_gemma":[0.0002666502,0.0001481522,0.0001703974,0.0001165876,0.0003211125,0.000334629,0.0002204405,0.0004072362,0.0006397432],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003068188,"about_ca_system_score_gemma":0.0001261369,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001175681,"about_ca_topic_score_gemma":0.001836168,"domain_scores_codex":[0.9998397,0.00003457561,0.000008696898,0.00003084576,0.00002164021,0.0000645439],"domain_scores_gemma":[0.9998633,0.0000570811,0.00002687896,0.00001653776,0.0000136666,0.00002240018],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004569035,0.0000172552,0.0001441199,0.00006951778,0.000008320199,0.00008191243,0.00002244863,0.0000809331,0.9956767,0.0003085055,0.0001100977,0.003023376],"study_design_scores_gemma":[0.000008145827,0.00005827369,0.0002334015,0.000001194004,0.000003575021,0.00005081762,0.000004632346,0.0001034434,0.9989522,0.00001446429,0.0005677073,0.000002241757],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870465,0.001276228,0.004045367,0.0002613304,0.00009035146,0.00003562868,0.0001995983,0.0003150059,0.006729967],"genre_scores_gemma":[0.9960579,0.0002713627,0.001419622,0.00007397465,0.000008751738,0.000007848532,0.00008241173,0.0000252315,0.002052891],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002170858,"threshold_uncertainty_score":0.00726223,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01166668392973411,"score_gpt":0.2014579341501744,"score_spread":0.1897912502204402,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}