{"id":"W2026493142","doi":"10.1139/v06-119","title":"Microwave-assisted N-nitroarylation of some pyrimidine and purine nucleobases","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Nucleobase; Pyrimidine; Chemistry; Purine; Microwave; Purine metabolism; Stereochemistry; Combinatorial chemistry; DNA; Organic chemistry; Enzyme; Biochemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002056598,0.0003411414,0.0002756318,0.0001897487,0.000199574,0.00008517292,0.0003481078,0.0002279138,0.0009296263],"category_scores_gemma":[0.0002092838,0.0001480066,0.0002272838,0.0001687512,0.0001405606,0.0001833232,0.0002198127,0.0004375271,0.0003134258],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000155837,"about_ca_system_score_gemma":0.0001648382,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004009863,"about_ca_topic_score_gemma":0.001309484,"domain_scores_codex":[0.9998665,0.00002532266,0.00001057383,0.00002802653,0.00005269458,0.00001681331],"domain_scores_gemma":[0.9999269,0.00001555489,0.00002465183,0.00001105326,0.00001257897,0.000009094435],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002306343,0.000007624145,0.00004338979,0.00007472714,0.00000543868,0.00007062512,0.00002426551,0.0000872538,0.9965545,0.0001759153,0.00003131419,0.002901864],"study_design_scores_gemma":[0.000006568099,0.0001661685,0.0006275596,0.000004760854,0.00001450303,0.0003775632,0.000006877738,0.0003077437,0.9942437,0.00005793113,0.00417935,0.000007315842],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9034384,0.009290848,0.07728308,0.0001610774,0.00009622076,0.0001206542,0.0003011748,0.0003199053,0.008988556],"genre_scores_gemma":[0.9591284,0.004659541,0.03041971,0.00006194274,0.0000351593,0.00006578615,0.0003642518,0.00005766638,0.005207493],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009296263,"threshold_uncertainty_score":0.003109872,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004611569778852694,"score_gpt":0.1814019617961171,"score_spread":0.1767903920172645,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}