{"id":"W2026699244","doi":"10.1039/c3dt53326c","title":"Reactions of ruthenium hydrides with ethyl-vinyl sulfide","year":2014,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"IMes; Chemistry; Medicinal chemistry; Carbene; Hydride; Ruthenium; Sulfide; Methanol; Organic chemistry; Catalysis; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001810937,0.0002730101,0.0002309317,0.00009401062,0.0001033964,0.0001688776,0.000317251,0.0002551874,0.001381225],"category_scores_gemma":[0.000171066,0.000175118,0.0002574616,0.0001198641,0.0001293269,0.0002449847,0.0002805994,0.0003117545,0.000409083],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002773577,"about_ca_system_score_gemma":0.0001805742,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000716806,"about_ca_topic_score_gemma":0.001491847,"domain_scores_codex":[0.9998502,0.00002381992,0.0000130509,0.00002899491,0.00003801965,0.00004603331],"domain_scores_gemma":[0.9999169,0.00001731052,0.00002355445,0.00001266955,0.00001435299,0.00001524135],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001024869,0.00001151858,0.00008585826,0.00006415858,0.00001010972,0.00009556283,0.00002974948,0.0001573087,0.9980938,0.0001351835,0.00004045266,0.00117377],"study_design_scores_gemma":[0.000006688222,0.00008467305,0.0002003662,0.000001934656,0.000003031353,0.000053096,0.000007453534,0.0002485868,0.998713,0.00001346779,0.0006651596,0.000002583529],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9925293,0.0008501956,0.002728149,0.00005848583,0.00003916373,0.00003687234,0.0001970335,0.0001152866,0.003445386],"genre_scores_gemma":[0.9941491,0.0004379354,0.002065604,0.00001784809,0.000007278313,0.00001234112,0.0002510082,0.00002148666,0.003037406],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001381225,"threshold_uncertainty_score":0.004620612,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01266375012401193,"score_gpt":0.248053801817729,"score_spread":0.235390051693717,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}