{"id":"W2027241082","doi":"10.1002/marc.200290012","title":"Atom‐Transfer Radical Polymerization of 2‐(<i>N,N</i>‐Dimethylamino)ethyl Acrylate","year":2002,"lang":"en","type":"article","venue":"Macromolecular Rapid Communications","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University; Polymer Source (Canada)","funders":"","keywords":"Polymer chemistry; Chemistry; Atom-transfer radical-polymerization; Monomer; Ethyl acrylate; Acrylate; Polymerization; Amine gas treating; Catalytic chain transfer; Copolymer; Methyl acrylate; Radical polymerization; Butyl acrylate; Chain transfer; Catalysis; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009952352,0.0002361637,0.0003074233,0.0001017996,0.0002526763,0.00003433732,0.001013786,0.0001713943,0.003377264],"category_scores_gemma":[0.00004392669,0.000259877,0.0001899251,0.0003745584,0.0003502888,0.0001682422,0.0001907133,0.0002652236,0.0000585146],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003178958,"about_ca_system_score_gemma":0.0000188314,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001883097,"about_ca_topic_score_gemma":0.000002329033,"domain_scores_codex":[0.9984183,0.0001320052,0.0005839224,0.00029221,0.0002841651,0.000289357],"domain_scores_gemma":[0.9973841,0.0001331016,0.0001590146,0.00214251,0.00008798577,0.00009326936],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009034341,0.0002829164,0.0001371363,0.00003882301,0.00007408506,0.000002514722,0.0004358629,0.00000420537,0.9247702,0.004229368,0.00002401308,0.06999182],"study_design_scores_gemma":[0.000505682,0.00002280245,0.0001707618,0.00006830988,0.00008208086,0.00001672551,0.00006759119,0.002116382,0.937178,0.0001580384,0.05929979,0.0003138833],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6775037,0.05261973,0.1699286,0.005319076,0.0002659317,0.000606178,0.0005112714,0.000782445,0.09246308],"genre_scores_gemma":[0.9930139,0.003226048,0.002661597,0.0001831313,0.00002831762,0.00006083645,0.0002725446,0.00006194516,0.0004917316],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3155101,"threshold_uncertainty_score":0.9999853,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02092300224200481,"score_gpt":0.2340892431223566,"score_spread":0.2131662408803518,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}