{"id":"W2027304248","doi":"10.1021/ma070368h","title":"Correlating Pyrene Excimer Formation with Polymer Chain Dynamics in Solution. Possibilities and Limitations","year":2007,"lang":"en","type":"article","venue":"Macromolecules","topic":"Surfactants and Colloidal Systems","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Excimer; Pyrene; Polystyrene; Chemistry; Fluorescence; Polymer; Monomer; Polymer chemistry; Styrene; Photochemistry; Kinetics; Yield (engineering); Materials science; Copolymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.003660509,0.0006772578,0.0006196378,0.0006319821,0.0003912275,0.001259498,0.0007921752,0.001042382,0.001209608],"category_scores_gemma":[0.005881403,0.0005166774,0.0004401007,0.0005169459,0.00074522,0.002171416,0.0006674779,0.0009323184,0.0004378729],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007867778,"about_ca_system_score_gemma":0.0007693905,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001041279,"about_ca_topic_score_gemma":0.0009360799,"domain_scores_codex":[0.9987738,0.0004104265,0.0001164752,0.0002980093,0.0002901737,0.0001111535],"domain_scores_gemma":[0.9950022,0.003327507,0.0004663018,0.0004621008,0.0006156405,0.000126282],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001963893,0.00004466698,0.004358473,0.0007488983,0.0000329633,0.0001401303,0.0001254578,0.001376439,0.9770552,0.001018094,0.00006586051,0.01483744],"study_design_scores_gemma":[0.000007630114,0.000208699,0.002415539,0.00004410948,0.00004068585,0.0003430692,0.0001107474,0.00904802,0.9836288,0.001138019,0.002995213,0.00001941375],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7971734,0.02115143,0.173528,0.001222346,0.0002065769,0.0003935836,0.000587216,0.0004751581,0.005262215],"genre_scores_gemma":[0.9192672,0.008112731,0.06820218,0.0002807819,0.00006873943,0.0004277138,0.0004487327,0.00009023348,0.003101722],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003660509,"threshold_uncertainty_score":0.01935887,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01297341551106636,"score_gpt":0.2168509226267794,"score_spread":0.203877507115713,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}