{"id":"W2027642932","doi":"10.1002/adsc.201100244","title":"Rhodium‐Catalyzed Aerobic Coupling between Aldehydes and Arenesulfinic Acid Salts: A Novel Synthesis of Aryl Ketones","year":2011,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Canada Research Chairs","keywords":"Chemistry; Rhodium; Aryl; Catalysis; Coupling reaction; Molecular oxygen; Coupling (piping); Sulfate; Organic chemistry; Sodium; Oxygen; Sodium azide; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002366235,0.0006140051,0.0003361026,0.0002084615,0.0001690796,0.000219607,0.0004036899,0.0002747458,0.001021845],"category_scores_gemma":[0.0001119089,0.0002117131,0.0002664161,0.0001599023,0.0002087401,0.0003664585,0.0003465269,0.0004893769,0.0006060855],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002331879,"about_ca_system_score_gemma":0.0004348485,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006541939,"about_ca_topic_score_gemma":0.001465164,"domain_scores_codex":[0.9998482,0.00002208252,0.00001935516,0.00002904243,0.00003893782,0.00004230689],"domain_scores_gemma":[0.9999274,0.000006003552,0.00001545188,0.00001094063,0.00001472748,0.00002542109],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007279983,0.00006910194,0.0001448311,0.0001978742,0.00002087933,0.0004303967,0.00008316174,0.0004476523,0.987999,0.001152896,0.0001942369,0.009187288],"study_design_scores_gemma":[0.00002863168,0.000440382,0.0005685065,0.0000090657,0.00003307334,0.000376732,0.00002307399,0.0005148089,0.9894843,0.0001100519,0.008388598,0.0000228569],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9089763,0.005956387,0.06128532,0.000406555,0.0003641196,0.0003339679,0.0006401038,0.0004853405,0.02155199],"genre_scores_gemma":[0.9716122,0.003805112,0.01651836,0.00005999117,0.00003157302,0.00007619392,0.0002782177,0.00003630974,0.007582001],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001021845,"threshold_uncertainty_score":0.003418386,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03152160078338562,"score_gpt":0.2501398762760031,"score_spread":0.2186182754926175,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}