{"id":"W2027653485","doi":"10.1021/om900669y","title":"Cationic Organomagnesium Complexes as Highly Active Initiators for the Ring-Opening Polymerization of ε-Caprolactone","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":86,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"","keywords":"Cationic polymerization; Chemistry; Polymerization; Monomer; Ring-opening polymerization; Polymer chemistry; Caprolactone; Ligand (biochemistry); Polymer; Copolymer; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003667647,0.0004382108,0.0002366499,0.0002841019,0.0001532334,0.0003986607,0.0003641268,0.0003643387,0.000997018],"category_scores_gemma":[0.0003295169,0.000250079,0.0001683478,0.0001715791,0.0002478385,0.0002766539,0.0002613373,0.0003619943,0.0003864162],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004249261,"about_ca_system_score_gemma":0.0002091689,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002020757,"about_ca_topic_score_gemma":0.0004438808,"domain_scores_codex":[0.999799,0.00004762435,0.00001576847,0.00003974631,0.00005684872,0.00004105236],"domain_scores_gemma":[0.9998201,0.00003496301,0.00006232206,0.00001192578,0.00002187667,0.00004876638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007543412,0.00001427681,0.00003178745,0.0000450932,0.000002942154,0.00003272666,0.00001849481,0.00008304878,0.9985359,0.0002072383,0.00002912821,0.0009238835],"study_design_scores_gemma":[0.00003998553,0.0001205812,0.0001319999,0.000003305782,0.000006746498,0.00005009167,0.000004433415,0.0003740823,0.9978903,0.00003113533,0.001342664,0.000004668481],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9768789,0.002075141,0.01681476,0.0001288602,0.000071738,0.0001182574,0.0001216731,0.000445656,0.003344985],"genre_scores_gemma":[0.9900175,0.0005818932,0.006768348,0.00005414634,0.00002193248,0.00004843455,0.0001016537,0.00005325332,0.002352816],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000997018,"threshold_uncertainty_score":0.003335297,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01145268146590388,"score_gpt":0.2389220043324606,"score_spread":0.2274693228665567,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}