{"id":"W2027681891","doi":"10.1134/s1070363208050253","title":"Sulfanylamide-containing coordination compounds of 3d-elements with 2,4-pentanedione bis-thiosemicarbazone and bis-4-phenylthiosemicarbazone","year":2008,"lang":"en","type":"article","venue":"Russian Journal of General Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Semicarbazone; Denticity; Deprotonation; Thermal decomposition; Coordination complex; Medicinal chemistry; Manganese; Cobalt; Stereochemistry; Inorganic chemistry; Crystal structure; Organic chemistry; Metal; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004186571,0.00025031,0.0007557926,0.0001063814,0.0001202215,0.00001848515,0.0001567689,0.0001077585,0.0001192305],"category_scores_gemma":[0.00008703215,0.0001807205,0.0001180331,0.0001899004,0.0002499624,0.0001513493,0.00004770154,0.000353759,7.186291e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008089533,"about_ca_system_score_gemma":0.0002542903,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001699227,"about_ca_topic_score_gemma":9.612662e-7,"domain_scores_codex":[0.9979697,0.00005582018,0.0008962214,0.0002192002,0.0005974024,0.0002616389],"domain_scores_gemma":[0.9984709,0.00005278123,0.0007544384,0.0002400895,0.0002460661,0.0002357176],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001099768,0.0001305696,0.02074162,0.0002328157,0.0002780252,0.0001304651,0.000206373,0.000007294144,0.9761485,0.00003934592,0.0003078007,0.0006773701],"study_design_scores_gemma":[0.004655776,0.001300134,0.01311145,0.0009167346,0.0003775923,0.00841964,0.0002937051,0.0002430879,0.9679789,0.0000455888,0.002304782,0.0003526434],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915456,0.002638992,0.000139144,0.0006139263,0.00006460389,0.0001119706,0.000006800208,0.0000136166,0.004865412],"genre_scores_gemma":[0.9869622,0.0003910022,0.01102871,0.0001038485,0.0003453966,0.000002794746,0.00001695854,0.00003389074,0.001115183],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01088956,"threshold_uncertainty_score":0.736957,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02265263786231851,"score_gpt":0.2384132484830374,"score_spread":0.2157606106207189,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}